Rhodium-Catalyzed C-H Activation Enabled by an Indium Metalloligand

被引：23
作者：
Yamada, Ryosuke [1 ]
Iwasawa, Nobuharu [1 ]
Takaya, Jun [1 ]
机构：
[1] Tokyo Inst Technol, Dept Chem, Sch Sci, Meguro Ku, Tokyo 1528551, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 48期
关键词：
C-H activation; indium; metalloligands; rhodium; Z-type ligands; ONLY LEWIS PAIRS; X-RAY CRYSTAL; COMPLEXES BEARING; LIGAND SYNTHESIS; REACTIVITY; NICKEL; HYDROGENATION; NITROGEN; CYCLOPENTADIENYL; AZIDES;
D O I：
10.1002/anie.201910197
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rhodium complexes with an indium metalloligand were successfully synthesized by utilizing a pyridine-tethered cyclopentadienyl ligand as a support for an In-Rh bond. The indium metalloligand dramatically changes the electronic and redox properties of the rhodium metal, thereby enabling catalysis of sp(2)C-H bond activation.
引用
收藏
页码：17251 / 17254
页数：4
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