Self-assembly and x-ray structure of a ten-component, three-dimensional metallosupramolecular cage

被引：176

作者：

Hartshorn, CM ^{[1
]}

Steel, PJ ^{[1
]}

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 06期

关键词：

D O I：

10.1039/a608081b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1,3,5-tris(pyrazol-1-ylmethyl)-2,4,6-triethylbenzene 7 with palladium chloride results in the self-assembly of a three-dimensional cage; an X-ray crystal structure determination shows that the cage is comprised of an octahedral arrangement of six palladium atoms bridged by a tetrahedral network of four molecules of the ligand and contains a (disordered) guest molecule of dimethyl sulfoxide.

引用

页码：541 / 542

页数：2

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