Highly active copper-catalysts for azide-alkyne cycloaddition

被引：127

作者：

Gonda, Zsombor ^{[1
]}

Novak, Zoltan ^{[1
]}

机构：

[1] Eotvos Lorand Univ, Dept Organ Chem, Inst Chem, Budapest, Hungary

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 03期

关键词：

CLICK CHEMISTRY; 1,3-DIPOLAR CYCLOADDITIONS; TERMINAL ALKYNES; COMPLEXES; LIGANDS; FUNCTIONALITY; LIGATION; SURFACES; POLYMER; TOOL;

D O I：

10.1039/b920790m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis-triphenylphosphano complexes of copper(I)-carboxylates serve as efficient catalysts for azide-alkyne cycloaddition. The triazole formation takes place straightforwardly at ambient temperature providing a wide variety of products with good yields in the presence of 0.005-0.05% catalyst.

引用

页码：726 / 729

页数：4

共 32 条

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