Thermal behavior research for co-combustion of furfural residue and oil shale semi-coke

被引:59
作者
Qin, Hong [1 ]
Wang, Wanli [1 ]
Liu, Hongpeng [1 ]
Zhang, Lidong [1 ]
Wang, Qing [1 ]
Shi, Chuangye [1 ]
Yao, Kewei [1 ]
机构
[1] Northeast Elect Power Univ, Engn Res Ctr Oil Shale Comprehens Utilizat, Minist Educ, Changchun Rd 169, Jilin 132012, Jilin, Peoples R China
关键词
Furfural residue; Semi-coke; Co-combustion; Synergy; Kinetics; THERMOGRAVIMETRIC ANALYSIS; COMPREHENSIVE UTILIZATION; TORREFIED CORNSTALK; PYROLYSIS KINETICS; COMBUSTION; BIOMASS; SEMICOKES; CHINESE; COALS;
D O I
10.1016/j.applthermaleng.2017.03.111
中图分类号
O414.1 [热力学];
学科分类号
摘要
The thermal behavior of Longkou oil shale semi-coke, furfural residue and their blends was researched in this paper. The experiment was carried out using TG-FTIR to research the combustion mechanism, under different heating rate (10, 20, 40 and 80 degrees C/min) and simulation of air condition (80% nitrogen: 20% oxygen). The oil shale semi-coke was blended with furfural residue in proportions from 20% to 100%. Two following factors were studied: heating rate and mixing ratio. The combustion behavior of semi-coke can be promoted furfural residue. And the synergistic effect was calculated by means of interaction coefficient f and the Relative Error of Mean Square root. The combustion of two samples can be divided into two stages, and three stages of co-combustion. Synergy occurred in every stage. At the same time, the co-combustion kinetics parameters were calculated by the Coats-Redfern method. The activation energy of the mixtures first decreased and then increased with the degree of reaction. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:19 / 25
页数:7
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