Simultaneous and Selective Detection of Environment Hazardous Metals in Water Samples by Using Flower and Christmas Tree Like Cerium Hexacyanoferrate Modified Electrodes

被引：20

作者：

Devadas, Balamurugan ^{[1
]}

Sivakumar, Mani ^{[1
]}

Chen, Shen-Ming ^{[1
]}

Rajkumar, Muniyandi ^{[2
]}

Hu, Chi-Chang ^{[2
]}

机构：

[1] Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol, Elect Anal & Bio Electrochem Lab, Taipei 106, Taiwan

[2] Natl Tsing Hua Univ, Dept Chem Engn, Lab Electrochem & Adv Mat, Hsinchu 30013, Taiwan

来源：

ELECTROANALYSIS | 2015年 / 27卷 / 11期

关键词：

Voltammetric; Cerium hexacaynoferrate; Heavy metal ions; water samples; ANODIC-STRIPPING VOLTAMMETRY; HEAVY-METALS; ELECTROCHEMICAL SYNTHESIS; TRACE-METALS; LEAD; CADMIUM; COPPER; IONS; SENSOR; SYSTEM;

D O I：

10.1002/elan.201500208

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

We report facile, template-free, surfactant-less flower and Christmas tree-like cerium hexacyanoferrate (CeHCF) modified electrodes for simultaneous measurement of environmentally hazardous metals. The hierarchical growth of CeHCF on electrode surface was controlled by electrodeposition time at constant potential. This CeHCF modified electrode exhibits a prominent electrocatalytic activity towards detection of heavy metal ions such as cadmium (Cd), copper (Cu), lead (Pb) and mercury (Hg). The peaks are separated well at CeHCF modified electrode. Well separated peaks for the detection of these heavy metals in lake and tap water samples indicating CeHCF modified electrode as successful electrode for the reported sensor.

引用

页码：2629 / 2636

页数：8

共 44 条

[1]

Anandhakumar S., 2011, AM J ANAL CHEM, V2, P470, DOI [10.4236/ajac.2011.24056, DOI 10.4236/AJAC.2011.24056]

[2] Antimony nanoparticle-multiwalled carbon nanotubes composite immobilized at carbon paste electrode for determination of trace heavy metals [J].

Ashrafi, Amir M. ;

Cerovac, Sandra ;

Mudric, Sanja ;

Guzsvany, Valeria ;

Husakova, Lenka ;

Urbanova, Iva ;

Vytras, Karel .

SENSORS AND ACTUATORS B-CHEMICAL, 2014, 191 :320-325

[3] Direct determination of heavy metals at picogram per gram levels in Greenland and Antarctic snow by double focusing inductively coupled plasma mass spectrometry [J].

Barbante, C ;

Bellomi, T ;

Mezzadri, G ;

Cescon, P ;

Scarponi, G ;

Morel, C ;

Jay, S ;

VanDeVelde, K ;

Ferrari, C ;

Boutron, CF .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1997, 12 (09) :925-931

[4] Simultaneous Determination of Cadmium, Lead, Copper and Mercury Ions Using Organofunctionalized SBA-15 Nanostructured Silica Modified Graphite - Polyurethane Composite Electrode [J].

Cesarino, Ivana ;

Cavalheiro, Eder T. G. ;

Brett, Christopher M. A. .

ELECTROANALYSIS, 2010, 22 (01) :61-68

[5] An environmental monitoring system for trace metals using stripping voltammetry [J].

Desmond, D ;

Lane, B ;

Alderman, J ;

Hill, M ;

Arrigan, DWM ;

Glennon, JD .

SENSORS AND ACTUATORS B-CHEMICAL, 1998, 48 (1-3) :409-414

[6]

Devadas B., 2014, ELECTROANAL, V26, P1

[7] Controlled electrochemical synthesis of new rare earth metal lutetium hexacyanoferrate on reduced graphene oxide and its application as a salicylic acid sensor [J].

Devadas, Balamurugan ;

Madhu, Rajesh ;

Chen, Shen-Ming ;

Yeh, Huai-Tse .

JOURNAL OF MATERIALS CHEMISTRY B, 2014, 2 (43) :7515-7523

[8]

Devadas B, 2012, INT J ELECTROCHEM SC, V7, P3339

[9]

Duruibe JO, 2007, INT J PHYS SCI, V2, P112

[10] Electrochemical Synthesis for Flowerlike and Fusiform Christmas-Tree-like Cerium Hexacyanoferrate(II) [J].

Feng, Liang-Dong ;

Gu, Miao-Miao ;

Yang, Yan-Li ;

Liang, Guo-Xi ;

Zhang, Jian-Rong ;

Zhu, Jun-Jie .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (20) :8743-8749

← 1 2 3 4 5 →