Synthesis, crystal structure and antimicrobial study of N,N,N′-tris(3-aminopropyl)ethylenediamine copper(II) diperchlorate

被引：0

作者：

Xu Xing-You ^{[1
]}

Xu Tong-Tao

Gao Jian

Wang Da-Qi

Lu Lu-De

Xu Guo-Xiang

机构：

[1] Huaihai Inst Technol, Key Marine Biotechnol Lab, Lianyungang 222005, Peoples R China

[2] Nanjing Univ Sci & Technol, Mat Chem Lab, Nanjing 210094, Peoples R China

[3] Lianyungang Tech Coll, Dept Chem Engn, Lianyungang 222006, Peoples R China

[4] Liaocheng Univ, Coll Chem & Chem Engn, Shandong 252059, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 26卷 / 01期

关键词：

N; '-tris(3-aminopropyl)ethylenediamine; copper compound; crystal structure; antimicrobial activity;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [Cu(C11H29N5)](ClO4)(2) was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The compound crystallizes in the monoclinic system, space group P2(1)/n with a=9.405(2), b=14.495(3), c=14.715(3) angstrom, beta=90.262(3)degrees, V=2006.1(7) angstrom(3), M-r=493.83, Z=4, F(000)=1028, D-c=1.635 g/cm(3), T=298(2) K,mu=1.403 mm(-1) and lambda=0.71073 angstrom. The structure was refined to R=0.0508 and wR=0.1250 for 2293 observed reflections with I>2 sigma(I). The Cu(II) atom possesses a five-coordinate CuN5 environment which shows a slightly distorted square-pyramidal geometry. Antimicrobial activity study found that. the complex is active against Salmonella species, Staphylococcus aureu, Bacillus pumilus and Bacillus coliforms.

引用

页码：121 / 125

页数：5

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