Synthesis and Optical Characterization of Hybrid Organic-Inorganic Heterofluorene Polymers

被引：32
作者：
Fell, Valentin H. K. [1 ]
Mikosch, Annabel [1 ]
Steppert, Ann-Kathrin [1 ]
Ogieglo, Wojciech [1 ]
Senol, Erdem [3 ]
Canneson, Damien [2 ]
Bayer, Manfred [2 ]
Schoenebeck, Franziska [3 ]
Greilich, Alex [2 ]
Kuehne, Alexander J. C. [1 ]
机构：
[1] Rhein Westfal TH Aachen, DWI Leibniz Inst Interact Mat, Forckenbeckstr 50, D-52076 Aachen, Germany
[2] Tech Univ Dortmund, Expt Phys 2, D-44221 Dortmund, Germany
[3] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany
来源：
MACROMOLECULES | 2017年 / 50卷 / 06期
关键词：
LIGHT-EMITTING-DIODES; SOLAR-CELLS; CONJUGATED POLYMERS; EMISSION; POLYFLUORENE; DERIVATIVES; POLYCARBAZOLE; ELECTRONICS; COPOLYMERS; ROUTE;
D O I：
10.1021/acs.macromol.6b02611
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We synthesize heterofluorene monomers with Si, Ge, N, As, Se, and Te occupying the 9-position of the fluorene motif, which are then polymerized by Suzuki coupling. The optical properties of the obtained polymers are investigated in their solid state. We compare and elucidate effects in the materials absorption, emission, quantum yield (Phi), and fluorescence lifetime. Moreover, we determine the refractive indices n and absorption coefficient k by variable angle spectroscopic ellipsometry (VASE). We show that in addition to already known C, Si, and N containing polyfluorenes also Ge and As containing polymers exhibit amplified spontaneous emission.
引用
收藏
页码：2338 / 2343
页数：6
相关论文
共 56 条
[1]   Germafluorenes: New Heterocycles for Plastic Electronics [J].
Allard, Nicolas ;
Aich, Reda Badrou ;
Gendron, David ;
Boudreault, Pierre-Luc T. ;
Tessier, Christian ;
Alem, Salima ;
Tse, Shing-Chi ;
Tao, Ye ;
Leclerc, Mario .
MACROMOLECULES, 2010, 43 (05) :2328-2333
[2]   High Stokes Shift Anilido-Pyridine Boron Difluoride Dyes [J].
Araneda, Juan F. ;
Piers, Warren E. ;
Heyne, Belinda ;
Parvez, Masood ;
McDonald, Robert .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (51) :12214-12217
[3]   Investigating work function tunable hole-injection/transport layers of electrodeposited polycarbazole network thin films [J].
Baba, A ;
Onishi, K ;
Knoll, W ;
Advincula, RC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (49) :18949-18955
[4]   A low-bandgap poly(2,7-carbazole) derivative for use in high-performance solar cells [J].
Blouin, Nicolas ;
Michaud, Alexandre ;
Leclerc, Mario .
ADVANCED MATERIALS, 2007, 19 (17) :2295-+
[5]   Poly(2,7-dibenzosilole): A blue light emitting polymer [J].
Chan, KL ;
McKiernan, MJ ;
Towns, CR ;
Holmes, AB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (21) :7662-7663
[6]   Synthesis, structure, and optoelectronic properties of phosphafluorene copolymers [J].
Chen, Run-Feng ;
Zhu, Rui ;
Fan, Qu-Li ;
Huang, Wei .
ORGANIC LETTERS, 2008, 10 (13) :2913-2916
[7]   Structural, electronic, and optical properties of 9-heterofluorenes: A quantum chemical study [J].
Chen, Run-Feng ;
Zheng, Chao ;
Fan, Qu-Li ;
huang, Wei .
JOURNAL OF COMPUTATIONAL CHEMISTRY, 2007, 28 (13) :2091-2101
[8]   Germafluorene conjugated copolymer-synthesis and applications in blue-light-emitting diodes and host materials [J].
Chen RunFeng ;
Zhu Rui ;
Zheng Chao ;
Liu ShuJuan ;
Fan QuLi ;
Huang Wei .
SCIENCE IN CHINA SERIES B-CHEMISTRY, 2009, 52 (02) :212-218
[9]   Morphology control in polycarbazole based bulk heterojunction solar cells and its impact on device performance [J].
Chu, Ta-Ya ;
Alem, Salima ;
Tsang, Sai-Wing ;
Tse, Shing-Chi ;
Wakim, Salem ;
Lu, Jianping ;
Dennler, Gilles ;
Waller, David ;
Gaudiana, Russell ;
Tao, Ye .
APPLIED PHYSICS LETTERS, 2011, 98 (25)
[10]   Light-induced charge transfer in hybrid composites of organic semiconductors and silicon nanocrystals [J].
Dietmueller, Roland ;
Stegner, Andre R. ;
Lechner, Robert ;
Niesar, Sabrina ;
Pereira, Rui N. ;
Brandt, Martin S. ;
Ebbers, Andre ;
Trocha, Martin ;
Wiggers, Hartmut ;
Stutzmann, Martin .
APPLIED PHYSICS LETTERS, 2009, 94 (11)
123456