Peroxidative oxidation of cycloalkane by di-, tetra- and polynuclear copper(II) complexes

被引：0

作者：

Nandi, Mahasweta ^{[1
]}

Roy, Partha ^{[2
]}

机构：

[1] Visva Bharati Univ, Integrated Sci Educ & Res Ctr, Santini Ketan 731235, W Bengal, India

[2] Jadavpur Univ, Dept Chem, Kolkata 700032, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2013年 / 52卷 / 10期

关键词：

Oxidation; Peroxidative oxidation; Reaction mechanism; Polynuclear complexes; Copper; STRUCTURAL CHARACTERIZATION; TRIETHANOLAMINE COMPLEXES; METAL-COMPLEXES; MILD CONDITIONS; ALKANES; CATALYSTS; CYCLOHEXANE; FUNCTIONALIZATION; HYDROPEROXIDATION; TETRANUCLEAR;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Di-, tetra- and polynuclear copper(II) complexes with N2O donor system, [Cu-2(L-1)(mu(2)-pz)(CH3COO)(2)] (1), [Cu-4(L-1)(2)(mu(4)-O)(mu(2)-CH3COO)(2)(mu(1,1)-N-3)(N-3)] (2) and [Cu-2(L-2)(mu(1,1)-N-3)(mu(1,3)-N-3)(2)](infinity) (3) respectively (where pz = pyrazolato, HL1 = 2,6-bis(morpholinomethyl)-4-tert-butylphenol and HL2 = 2,6-bis(morpholinomethyl)-4-methylphenol) have been employed as catalysts for the peroxidative oxidation of cyclohexane and cycloheptane in the presence of hydrogen peroxide as the oxidant at room temperature and under atmospheric pressure. The oxidized products of cyclohexane are cyclohexanol and cyclohexanone, whereas cycloheptane is oxidized to cycloheptanol and cycloheptanone.

引用

页码：1263 / 1268

页数：6

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