Aminopolycarboxylic acid functionalized adsorbents for heavy metals removal from water

被引：215

作者：

Repo, Eveliina ^{[1
]}

Warchol, Jolanta K. ^{[2
]}

Bhatnagar, Amit ^{[3
]}

Mudhoo, Ackmez ^{[4
]}

Sillanpaa, Mika ^{[1
]}

机构：

[1] Lappeenranta Univ Technol, LUT Savo Sustainable Technol, Lab Green Chem, FI-50130 Mikkeli, Finland

[2] Rzeszow Univ Technol, Dept Water Purificat & Protect, PL-35959 Rzeszow, Poland

[3] Linnaeus Univ, Fac Hlth & Life Sci, Dept Biol & Environm Sci, SE-39182 Kalmar, Sweden

[4] Univ Mauritius, Fac Engn, Dept Chem & Environm Engn, Reduit, Mauritius

来源：

WATER RESEARCH | 2013年 / 47卷 / 14期

关键词：

Surface functionalization; Aminopolycarboxylic acid; Chelating agent; Heavy metals; Water treatment; Adsorption; RARE-EARTH-ELEMENTS; LAYERED DOUBLE HYDROXIDES; CHELATION ION CHROMATOGRAPHY; IMINODIACETIC ACID; TRACE-METALS; ICP-MS; TRANSITION-METALS; AQUEOUS-SOLUTIONS; WASTE-WATER; ONLINE PRECONCENTRATION;

D O I：

10.1016/j.watres.2013.06.020

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Due to the excellent chelating properties of aminopolycarboxylic acid (APCAs), they can be used for the removal of metals from contaminated waters. This paper reviews the research results obtained for both commercial and self-prepared adsorbents functionalized with four most common APCAs: iminodiacetic acid (IDA), nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), and diethylenetriaminepentaacetic acid (DTPA). The structural characteristics and unique metal binding properties of these chelating adsorbents are presented. The theory of the adsorption phenomena is discussed based on the kinetics of adsorption, equilibrium adsorption isotherm models, and thermodynamic models. The most important applications of APCA-functionalized adsorbents are also described. APCA-functionalized adsorbents are found to be highly promising materials for metal removal from contaminated waters. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：4812 / 4832

页数：21

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