Effect of acid catalyst on structural transformation and hydrolysis of cellulose in hydrothermal conditions

被引：30

作者：

Deguchi, Shigeru ^{[1
]}

Tsujii, Kaoru ^{[2
]}

Horikoshi, Koki ^{[1
]}

机构：

[1] Japan Agcy Marine Earth Sci & Technol, Extremobiosphere Res Ctr, Yokosuka, Kanagawa 2370061, Japan

[2] Hokkaido Univ, Nanotechnol Res Ctr, Res Inst Elect Sci, Kita Ku, Sapporo, Hokkaido 0010021, Japan

来源：

GREEN CHEMISTRY | 2008年 / 10卷 / 06期

关键词：

D O I：

10.1039/b803384f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of H2SO4 on the crystalline-to-amorphous transformation and hydrolysis of cellulose in water at high temperatures and high pressures was revealed for the first time by using in situ high-resolution optical microscopy.

引用

页码：623 / 626

页数：4

共 34 条

[1] NONCATALYTIC CONVERSION OF CELLULOSE IN SUPERCRITICAL AND SUBCRITICAL WATER [J].

ADSCHIRI, T ;

HIROSE, S ;

MALALUAN, R ;

ARAI, K .

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1993, 26 (06) :676-680

[2]

ATWELL WA, 1988, CEREAL FOOD WORLD, V33, P306

[3] HYDROTHERMAL DEGRADATION OF POLYMERS DERIVED FROM PLANTS [J].

BOBLETER, O .

PROGRESS IN POLYMER SCIENCE, 1994, 19 (05) :797-841

[4] Flow cell for in situ optical microscopy in water at high temperatures and pressures up to supercritical state [J].

Deguchi, S ;

Tsujii, K .

REVIEW OF SCIENTIFIC INSTRUMENTS, 2002, 73 (11) :3938-3941

[5]

Deguchi S, 2008, GREEN CHEM, V10, P191, DOI 10.1039/B713655B

[6] Supercritical water: a fascinating medium for soft matter [J].

Deguchi, Shigeru ;

Tsujii, Kaoru .

SOFT MATTER, 2007, 3 (07) :797-803

[7] Preparation and characterisation of nanofibrous cellulose plate as a new solid support for microbial culture [J].

Deguchi, Shigeru ;

Tsudome, Mikiko ;

Shen, Yihong ;

Konishi, Satoshi ;

Tsujii, Kaoru ;

Ito, Susumu ;

Horikoshi, Koki .

SOFT MATTER, 2007, 3 (09) :1170-1175

[8] Cooking cellulose in hot and compressed water [J].

Deguchi, Shigeru ;

Tsujii, Kaoru ;

Horikoshi, Koki .

CHEMICAL COMMUNICATIONS, 2006, (31) :3293-3295

[9] Viscosity measurements of water at high temperatures and pressures using dynamic light scattering [J].

Deguchi, Shigeru ;

Ghosh, Swapan K. ;

Alargova, Rossitza G. ;

Tsujii, Kaoru .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (37) :18358-18362

[10] A comparative study on chemical conversion of cellulose between the batch-type and flow-type systems in supercritical water [J].

Ehara, K ;

Saka, S .

CELLULOSE, 2002, 9 (3-4) :301-311

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