Anomalous thermal behaviour of polyimide at very low temperatures

被引:1
作者
Gottardi, E [1 ]
Peroni, I
Peruzzi, A
Ponti, G
Ventura, G
机构
[1] Univ Florence, Dept Phys, I-50127 Florence, Italy
[2] Univ Florence, Dept Energet, I-50139 Florence, Italy
关键词
D O I
10.1016/S0920-5632(99)00608-8
中图分类号
O412 [相对论、场论]; O572.2 [粒子物理学];
学科分类号
摘要
The thermal conductivity of an aromatic polyimide sheet (Upilex R) in the 0.1 divided by 1K range was measured. A conductivity k = alpha.T-n, with alpha = (1.50 +/- 0.06).10(-5) W/cmK(n+1) and n = 1.00 +/- 0.03, which is substantially different from what predicted by the tunneling model, was found. The linear dependence on temperature, which reveals the presence of crystalline units inside the sample, has been explained within the framework of the structure scattering theory, together with the standard tunneling model, and the size of the crystallites has been estimated. Our results are compared with the thermal conductivity of other semicrystalline materials.
引用
收藏
页码:581 / 584
页数:4
相关论文
共 15 条
[1]   ANOMALOUS LOW-TEMPERATURE THERMAL PROPERTIES OF GLASSES AND SPIN GLASSES [J].
ANDERSON, PW ;
HALPERIN, BI ;
VARMA, CM .
PHILOSOPHICAL MAGAZINE, 1972, 25 (01) :1-&
[2]   THE THERMAL-PROPERTIES OF A SEMICRYSTALLINE POLYMER AT VERY LOW-TEMPERATURES [J].
FINLAYSON, DM ;
MASON, PJ .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1985, 18 (09) :1777-1789
[3]   STRUCTURE SCATTERING AND THE THERMAL-CONDUCTIVITY OF A SEMICRYSTALLINE POLYMER [J].
FINLAYSON, DM ;
MASON, PJ .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1985, 18 (09) :1791-1802
[4]   LOCALIZED STATES IN GLASSES [J].
GALPERIN, YM ;
KARPOV, VG ;
KOZUB, VI .
ADVANCES IN PHYSICS, 1989, 38 (06) :669-737
[5]  
GREIG D, 1983, J PHYS C SOLID STATE, V16, P1051, DOI 10.1088/0022-3719/16/29/006
[6]  
Karpov V.G., 1983, ZH EKSP TEOR FIZ, V57, P439
[7]   THERMAL-CONDUCTIVITY OF SOME INSULATING MATERIALS MATERIALS BELOW 1-K [J].
LOCATELLI, M ;
ARNAUD, D ;
ROUTIN, M .
CRYOGENICS, 1976, 16 (06) :374-375
[8]   THERMAL CONDUCTION IN GLASSES AND POLYMERS AT LOW-TEMPERATURES [J].
MORGAN, GJ ;
SMITH, D .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1974, 7 (04) :649-664
[9]   THERMAL-CONDUCTIVITY OF SOME COMMON CRYOSTAT MATERIALS BETWEEN 0.05 AND 2-K [J].
OLSON, JR .
CRYOGENICS, 1993, 33 (07) :729-731
[10]   Tunneling States in Amorphous Solids [J].
Phillips, W. A. .
JOURNAL OF LOW TEMPERATURE PHYSICS, 1972, 7 (3-4) :351-360