Selective oxidation of m-phenoxytoluene to m-phenoxybenzaldehyde with methanol as an additive in acetic acid

被引：1

作者：

Yin, GC ^{[1
]}

Xi, ZW ^{[1
]}

Cao, GY ^{[1
]}

Fan, SH ^{[1
]}

Hai, XD ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

APPLIED CATALYSIS A-GENERAL | 1999年 / 185卷 / 02期

关键词：

acetic acid/methanol solvents; m-phenoxytoluene; m-phenoxybenzaldehyde; oxidation; cobalt bromide catalyst;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

With addition of methanol in acetic acid solvent, m-phenoxytoluene could be oxidized to m-phenoxybenzaldehyde selectively by a cobalt bromide catalyst. Paratemters such as the ratio of Co/Br and the reaction time of m-phenoxytoluene oxidation as well as visible spectra of cobalt bromide in acetic acid/methanol solvents, were also investigated. Addition of methanol caused the oxidation of aldehydes to proceed more slowly than it did solely in acetic acid solvent. The decrease of cobaltous-multibromides in acetic acid/methanol solvents was responsible for the improvement in the selective oxidation of m-phenoxytoluene. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：277 / 281

页数：5

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