A one-pot approach for conversion of fructose to 2,5-diformylfuran by combination of Fe3O4-SBA-SO3H and K-OMS-2

被引：168

作者：

Yang, Zhen-Zhen ^{[1
]}

Deng, Jin ^{[1
]}

Pan, Tao ^{[1
]}

Guo, Qing-Xiang ^{[1
]}

Fu, Yao ^{[1
]}

机构：

[1] Univ Sci & Technol China, Anhui Prov Key Lab Biomass Clean Energy, Dept Chem, Hefei 230026, Peoples R China

来源：

GREEN CHEMISTRY | 2012年 / 14卷 / 11期

基金：

中国国家自然科学基金;

关键词：

AEROBIC OXIDATION; LIGNOCELLULOSIC BIOMASS; SELECTIVE OXIDATION; BENZYL ALCOHOL; EFFICIENT; CATALYSTS; DERIVATIVES; CHEMICALS; TRANSFORMATION; AGENTS;

D O I：

10.1039/c2gc35947b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have demonstrated an efficient, selective and environmentally benign heterogeneous catalyst (K-OMS-2) for aerobic oxidation of 5-HMF to 2,5-DFF. In addition, a combination of Fe3O4-SBA-SO3H and K-OMS-2 successfully catalyzed direct synthesis of 2,5-DFF from fructose via acid-catalyzed dehydration and successive aerobic oxidation in one-pot reaction.

引用

页码：2986 / 2989

页数：4

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