Photocatalytic activity of TiO2 nanofibers sensitized with ZnS quantum dots

被引:48
作者
Chaguetmi, Samiha [1 ,2 ,3 ]
Mammeri, Fayna [1 ]
Nowak, Sophie [1 ]
Decorse, Philippe [1 ]
Lecoq, Helene [1 ]
Gaceur, Meriem [1 ]
Ben Naceur, Jamila [4 ]
Achour, Slimane [3 ]
Chtourou, Radhouane [4 ]
Ammar, Souad [1 ]
机构
[1] Univ Paris Diderot, UMR CNRS 7086, F-75205 Paris 13, France
[2] Univ 20 Aout 1955 Skikda, Skikda, Algeria
[3] Univ Mentouri, Lab Ceram, Constantine, Algeria
[4] Ctr Rech & Technol Energie, Lab Photovolta, Hammam Lif 2050, Tunisia
关键词
TRIBOLOGICAL BEHAVIOR; NANOTUBE ARRAYS; NANOPARTICLES; DEGRADATION; FABRICATION; TITANIA; NANOWIRES; SURFACE; OXYGEN; WATER;
D O I
10.1039/c2ra21684a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ZnS-TiO2 hetero-nanostructured photocatalysts were synthesized by the impregnation of ZnS quantum dots (QDs) on the surface of TiO2 nanofibers. Samples were characterized by X-ray diffraction (XRD), field emission gun scanning electron microscopy (FEG-SEM), X-ray photoelectron spectroscopy (XPS) and UV-visible diffuse reflectance spectroscopy. The photocatalytic activity of the prepared nanostructures was assessed by the photodegradation of methylene blue in an aqueous solution under UV irradiation. It was found that titanium dioxide impregnated with ZnS QDs increased photocatalytic activity. We demonstrated that methylene blue was more efficiently photodegraded by UV irradiation using ZnS-TiO2 heterogeneous photocatalysts than using pristine TiO2 nanofibers.
引用
收藏
页码:2572 / 2580
页数:9
相关论文
共 60 条
[1]   General predictive syntheses of cubic, hexagonal, and lamellar silica and titania mesostructured thin films [J].
Alberius, PCA ;
Frindell, KL ;
Hayward, RC ;
Kramer, EJ ;
Stucky, GD ;
Chmelka, BF .
CHEMISTRY OF MATERIALS, 2002, 14 (08) :3284-3294
[2]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[3]   Annealing effects on microstructural and optical properties of Nanostructured-TiO2 thin films prepared by solegel technique [J].
Ben Naceur, J. ;
Gaidi, M. ;
Bousbih, F. ;
Mechiakh, R. ;
Chtourou, R. .
CURRENT APPLIED PHYSICS, 2012, 12 (02) :422-428
[4]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[5]   THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS [J].
CHOI, WY ;
TERMIN, A ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) :13669-13679
[6]   TiO2 anatase thin films deposited by spray pyrolysis of an aerosol of titanium diisopropoxide [J].
Conde-Gallardo, A ;
Guerreri, M ;
Castillo, N ;
Soto, AB ;
Fragoso, R ;
Cabañas-Moreno, JG .
THIN SOLID FILMS, 2005, 473 (01) :68-73
[7]  
Coronado D.R., 2008, NANOTECHNOLOGY, V19, DOI DOI 10.1088/0957-4484/19/14/145605
[8]   A solid state solar cell using sol-gel processed material and a polymer [J].
Fan, Q ;
McQuillin, B ;
Bradley, DDC ;
Whitelegg, S ;
Seddon, AB .
CHEMICAL PHYSICS LETTERS, 2001, 347 (4-6) :325-330
[9]   The fabrication and switchable superhydrophobicity of TiO2 nanorod films [J].
Feng, XJ ;
Zhai, J ;
Jiang, L .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (32) :5115-5118
[10]   TIME-RESOLVED OPTICAL STUDY ON THE CHARGE-CARRIER DYNAMICS IN A TIO2/AGI SANDWICH COLLOID [J].
FITZMAURICE, D ;
FREI, H ;
RABANI, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (22) :9176-9181