Accelerating the Controlled Synthesis of Metal-Organic Frameworks by a Microfluidic Approach: A Nanoliter Continuous Reactor

被引：117

作者：

Paseta, Lorena

Seoane, Beatriz

Julve, Daniel

Sebastian, Victor

Tellez, Carlos

Coronas, Joaquin ^{[1
]}

机构：

[1] Univ Zaragoza, Chem & Environm Engn Dept, Zaragoza 50018, Spain

来源：

ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 19期

关键词：

segmented microfluidics; continuous synthesis; metal-organic framework; dicarboxylate; MIL-88B; CU-3(BTC)(2) HKUST-1; FLOW SYNTHESIS; PARTICLE-SIZE; NANOPARTICLES; CRYSTALS; COATINGS; ROUTE;

D O I：

10.1021/am4029872

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Segmented microfluidics was applied to the ultrafast crystallization of dicarboxylate based MIL-88B type metal-organic frameworks (MOFs; Fe-MIL-88B-NH2, Fe-MIL-88B, and Fe-MIL-88B-Br). Particular attention was paid to the influence of the temperature, residence time, and slug volume on the size and crystal size distribution of the MOFs. Average sizes in the 90-900 nm range with relatively narrow crystal size distributions were obtained with residence times as short as 20 s depending on the MOF type and synthesis conditions.

引用

收藏

页码：9405 / 9410

页数：6

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