A simple way of recycling of homogeneous catalyst in Suzuki reaction

被引:5
|
作者
Manjunatha, Sulur G. [1 ]
Rangappa, Paramashivappa [1 ]
Sythana, Sureshkumar [1 ]
Babu, Sureshbabu M. [1 ]
Tadiparthi, Krishnaji [1 ]
Gundala, Chennakrishnareddy [1 ]
机构
[1] AstraZeneca India Pvt Ltd, Pharmaceut Dev, Bangalore 560024, Karnataka, India
关键词
homogeneous catalyst; catalyst recycling; Suzuki reaction; Pd-100; Pd-106; Pd-118; CROSS-COUPLING REACTIONS; ARYL CHLORIDES; PALLADIUM; SONOGASHIRA; MIYAURA; HALIDES; HECK;
D O I
10.1080/17518253.2012.705896
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple and practical method of recycling homogeneous catalysts in the Suzuki reaction using appropriate work up conditions is reported here. The commonly used and commercially available homogeneous catalysts 1 (Pd-100) dichlorobis(tri-phenylphosphine)palladium(II), 2 (Pd-106) dichloro[1,1-bis(diphenylphosphino)ferrocene]palladium(II)-dichloromethane adduct, and 3 (Pd-118) 1,1-bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) selected for our study and were recycled successfully for three times using simple acidic and basic work up conditions depending on the presence of amino or carboxylic acid functional group in the product.
引用
收藏
页码:77 / 87
页数:11
相关论文
共 50 条
  • [31] A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling
    Chen, Zupeng
    Vorobyeva, Evgeniya
    Mitchell, Sharon
    Fako, Edvin
    Ortuno, Manuel A.
    Lopez, Nuria
    Collins, Sean M.
    Midgley, Paul A.
    Richard, Sylvia
    Vile, Gianvito
    Perez-Ramirez, Javier
    NATURE NANOTECHNOLOGY, 2018, 13 (08) : 702 - +
  • [32] A practical and simple method of recycling catalyst in asymmetric aminohydroxylation of Olefins
    Sun, Xiao Li
    Jin, Ying
    He, Wei
    Nan, Peng Juan
    Zhang, Sheng Yong
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2007, 28 (08) : 1422 - 1424
  • [33] Suzuki reaction: mechanistic multiplicity versus exclusive homogeneous or exclusive heterogeneous catalysis
    Kurokhtina, Anna A.
    Schmidt, Alexander F.
    ARKIVOC, 2009, : 185 - +
  • [34] Linear scaling relationships and volcano plots in homogeneous catalysis - revisiting the Suzuki reaction
    Busch, Michael
    Wodrich, Matthew D.
    Corminboeuf, Clemence
    CHEMICAL SCIENCE, 2015, 6 (12) : 6754 - 6761
  • [35] Suzuki-coupling reaction using immobilized catalyst membrane microchip
    Ueno, M
    Moriya, S
    Hisamoto, H
    Nakai, T
    Uozumi, Y
    Kitamori, T
    Micro Total Analysis Systems 2004, Vol 1, 2005, (296): : 471 - 473
  • [36] Si-Thiol supported palladium catalyst for Suzuki coupling reaction
    Huang, Zuo-Gang
    Liu, Rui
    Zhang, Li
    Ni, Chaoying
    Li, Harry
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [37] An Efficient Recyclable Polymer Supported Palladium Catalyst for Suzuki Reaction in Water
    Sruthi, Pambingal Rajan
    Roopak, Ramakrishnan
    Anas, Saithalavi
    CHEMISTRYSELECT, 2023, 8 (08):
  • [38] Cyclopalladated ferrocenylimine: a highly effective catalyst for the borylation/suzuki coupling reaction
    Ma, Ning
    Zhu, Zhiwu
    Wu, Yangjie
    TETRAHEDRON, 2007, 63 (22) : 4625 - 4629
  • [39] Efficient and recyclable dendritic Buchwald-type catalyst for the Suzuki reaction
    Lemo, Julietta
    Heuze, Karine
    Astruc, Didier
    CHEMICAL COMMUNICATIONS, 2007, (42) : 4351 - 4353
  • [40] Preparation and Suzuki Reaction Performance of Pectin-supported Palladium Catalyst
    Zhou Wenjun
    Zhou Yu
    Zhang Xiazhong
    Zeng Bin
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2016, 37 (04): : 669 - 673