A simple way of recycling of homogeneous catalyst in Suzuki reaction

被引：5

作者：

Manjunatha, Sulur G. ^{[1
]}

Rangappa, Paramashivappa ^{[1
]}

Sythana, Sureshkumar ^{[1
]}

Babu, Sureshbabu M. ^{[1
]}

Tadiparthi, Krishnaji ^{[1
]}

Gundala, Chennakrishnareddy ^{[1
]}

机构：

[1] AstraZeneca India Pvt Ltd, Pharmaceut Dev, Bangalore 560024, Karnataka, India

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2013年 / 6卷 / 01期

关键词：

homogeneous catalyst; catalyst recycling; Suzuki reaction; Pd-100; Pd-106; Pd-118; CROSS-COUPLING REACTIONS; ARYL CHLORIDES; PALLADIUM; SONOGASHIRA; MIYAURA; HALIDES; HECK;

D O I：

10.1080/17518253.2012.705896

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and practical method of recycling homogeneous catalysts in the Suzuki reaction using appropriate work up conditions is reported here. The commonly used and commercially available homogeneous catalysts 1 (Pd-100) dichlorobis(tri-phenylphosphine)palladium(II), 2 (Pd-106) dichloro[1,1-bis(diphenylphosphino)ferrocene]palladium(II)-dichloromethane adduct, and 3 (Pd-118) 1,1-bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) selected for our study and were recycled successfully for three times using simple acidic and basic work up conditions depending on the presence of amino or carboxylic acid functional group in the product.

引用

页码：77 / 87

页数：11

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