Multivariable kinetic theory of the first order phase transitions

被引:15
作者
Alekseechkin, NV [1 ]
机构
[1] Kharkov Inst Phys & Technol, Natl Sci Ctr, UA-61108 Kharkov, Ukraine
关键词
D O I
10.1063/1.2178781
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The problem of calculation of the steady state homogeneous nucleation rate in the multidimensional space of the variables describing a nucleus is considered. Within the framework of the theory proposed, expressions for the nucleation rate and the steady state distribution function of nuclei are derived. The expression for the nucleation rate is invariant with respect to the space dimensionality and, in particular, involves the result of the one-dimensional theory. The distribution function is obtained in the initial, physical variables. In connection with the analysis of restrictions on the current direction, the question of symmetry of the matrix of diffusivities is considered; on the basis of the detailed balance principle it is shown that this matrix is symmetric. The question of normalizing the equilibrium distribution functions is investigated and the physical picture of the equilibrium state is described. The procedure of reducing the multidimensional theory to the one-dimensional one is described.
引用
收藏
页数:13
相关论文
共 28 条
[1]  
ALEKSEECHKIN NV, 1993, FIZ TVERD TELA+, V35, P929
[2]  
[Anonymous], B ACAD SCI USSR PHYS
[3]   DIRECTION OF THE NUCLEATION CURRENT THROUGH THE SADDLE-POINT IN THE BINARY NUCLEATION THEORY AND THE SADDLE-POINT AVOIDANCE [J].
BEREZHKOVSKII, LM ;
ZITSERMAN, VY .
JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (08) :3331-3336
[4]  
BRENER EA, 1983, ZH EKSP TEOR FIZ+, V85, P2107
[5]  
DERJAGUIN BV, 1977, ZH EKSP TEOR FIZ+, V73, P1831
[6]   HOMOGENEOUS NUCLEATION AND GROWTH OF DROPLETS IN VAPOURS [J].
FEDER, J ;
RUSSELL, KC ;
LOTHE, J ;
POUND, GM .
ADVANCES IN PHYSICS, 1966, 15 (57) :111-&
[7]  
Frenkel Y.I., 1946, KINETIC THEORY LIQUI
[8]   NUMERICAL MODELING OF CRYSTAL NUCLEATION IN GLASSES [J].
GREER, AL ;
EVANS, PV ;
HAMERTON, RG ;
SHANGGUAN, DK ;
KELTON, KF .
JOURNAL OF CRYSTAL GROWTH, 1990, 99 (1-4) :38-45
[9]  
GRININ AP, 1989, TEOR MAT FIZ, V80, P418
[10]  
KAGAN Y, 1960, ZH FIZ KHIM+, V34, P92