Solvent dependent synthesis of micro- and nano- crystalline phosphinate based 1D tubular MOF: structure and CO2 adsorption selectivity

被引：47

作者：

Bataille, Thierry ^{[2
]}

Bracco, Silvia ^{[1
]}

Comotti, Angiolina ^{[1
]}

Costantino, Ferdinando ^{[3
,5
]}

Guerri, Annalisa ^{[4
]}

Ienco, Andrea ^{[5
]}

Marmottini, Fabio ^{[6
]}

机构：

[1] Univ Milano Bicocca, Dept Mat Sci, I-20125 Milan, Italy

[2] Univ Rennes 1, CNRS, Sci Chim Rennes UMR 6226, F-35042 Rennes, France

[3] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[4] Univ Florence, Dipartimento Chim, I-50019 Florence, Italy

[5] CNR ICCOM, I-50019 Florence, Italy

[6] Univ Perugia, Dipartimento Ingn Civile & Ambientale, I-06123 Perugia, Italy

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 21期

关键词：

POROUS COORDINATION POLYMER; METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE; METHANE; DESIGN; CHAIN; TUBE; NANOCRYSTALS; POLYMORPHISM; STORAGE;

D O I：

10.1039/c2ce26138c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel porous tubular 1D-MOF, built from Cu(II), 1,2-bis(4-pyridyl) ethane and P, P'-diphenyl-diphosphinate, has been prepared by an easy and direct self-assembly process in either needle microcrystal or nanorod form depending on the synthesis conditions. The CO2 absorption kinetics drastically increased from the micrometric crystals to the nanorods. The selectivity towards other gases and polar solvents was also investigated.

引用

页码：7170 / 7173

页数：4

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