A study on the activity of CaO-based sorbents for capturing CO2 in clean energy processes

被引：66

作者：

Wang, Jinsheng ^{[1
]}

Manovic, Vasilije ^{[1
]}

Wu, Yinghai ^{[1
]}

Anthony, Edward J. ^{[1
]}

机构：

[1] Nat Resources Canada, CanmetENERGY, Ottawa, ON K1A 1M1, Canada

来源：

APPLIED ENERGY | 2010年 / 87卷 / 04期

关键词：

CO2; capture; Solid sorbents; Long-term or residual activity; ENHANCED HYDROGEN-PRODUCTION; CARBON-DIOXIDE CAPTURE; FLUIDIZED-BED; STEAM REACTIVATION; DECAY BEHAVIOR; CALCINATION; COMBUSTION; CAPACITY; SORPTION; CYCLE;

D O I：

10.1016/j.apenergy.2009.08.010

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

CaO-based regenerative sorbents for CO2 capture in power generation and H-2 production are receiving growing attention. A major challenge for this technology is the decay of sorbent activity with increasing number of the sorption/regeneration cycles. Evaluation of long-term sorbent activity currently requires substantial experimental work. In this study, the dependence of the activity on the number of sorption/regeneration cycles is examined, and the apparent dependence on the number of cycles is related to the duration of sorbent regeneration. By relating the decay in activity of the sorbent to its decrease in surface area due to sintering, interesting insights can be drawn. A method for determination of the long-term activity has been proposed, which can greatly reduce the experimental work for sorbent development and process evaluation. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.

引用

页码：1453 / 1458

页数：6

共 46 条

[11] Enhanced hydrogen production from biomass with in situ carbon dioxide capture using calcium oxide sorbents [J].

Florin, Nicholas H. ;

Harris, Andrew T. .

CHEMICAL ENGINEERING SCIENCE, 2008, 63 (02) :287-316

[12] Hydrogen production from biomass coupled with carbon dioxide capture: The implications of thermodynamic equilibrium [J].

Florin, Nicholas H. ;

Harris, Andrew T. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (17) :4119-4134

[13]

Fogler H. S, 1999, ELEMENTS CHEM REACTI, V3rd

[14]

FUERTES AB, 1993, CHEM ENG RES DES, V71, P69

[15] CO2 capture capacity of CaO in long series of carbonation/calcination cycles [J].

Grasa, Gemma S. ;

Abanades, J. Carlos .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (26) :8846-8851

[16] Sorption-enhanced hydrogen production: A review [J].

Harrison, Douglas P. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (17) :6486-6501

[17] Repetitive carbonation-calcination reactions of Ca-based sorbents for efficient CO2 sorption at elevated temperatures and pressures [J].

Kuramoto, K ;

Fujimoto, S ;

Morita, A ;

Shibano, S ;

Suzuki, Y ;

Hatano, H ;

Lin, SY ;

Harada, M ;

Takarada, T .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (05) :975-981

[18] Ca-based sorbent looping combustion for CO2 capture in pilot-scale dual fluidized beds [J].

Lu, Dennis Y. ;

Hughes, Robin W. ;

Anthony, Edward J. .

FUEL PROCESSING TECHNOLOGY, 2008, 89 (12) :1386-1395

[19] Change of CO2 carrying capacity of CaO in isothermal recarbonation-decomposition cycles [J].

Lysikov, Anton I. ;

Salanov, Aleksey N. ;

Okunev, Aleksey G. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (13) :4633-4638

[20] Economics of CO2 capture using the calcium cycle with a pressurized fluidized bed combustor [J].

MacKenzie, A. ;

Granatstein, D. L. ;

Anthony, E. J. ;

Abanades, J. C. .

ENERGY & FUELS, 2007, 21 (02) :920-926

← 1 2 3 4 5 →