Polynuclear halide complexes of Bi(III): From structural diversity to the new properties

被引：233
作者：
Adonin, Sergey A. [1 ,2 ]
Sokolov, Maxim N. [1 ,2 ]
Fedin, Vladimir P. [1 ,2 ]
机构：
[1] Nikolaev Inst Inorgan Chem SB RAS, Lavrentieva St 3, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia
来源：
COORDINATION CHEMISTRY REVIEWS | 2016年 / 312卷
基金：
俄罗斯科学基金会;
关键词：
Bismuth; Halide complexes; Polynuclear complexes; Halides; INORGANIC-ORGANIC HYBRIDS; CENTER-DOT 2ME(2)C=O; X-RAY-DIFFRACTION; CRYSTAL-STRUCTURE; PHASE-TRANSITIONS; DIELECTRIC-PROPERTIES; OPTICAL-PROPERTIES; MOLECULAR MOTIONS; BISMUTH IODIDE; PENTACHLOROBISMUTHATE III;
D O I：
10.1016/j.ccr.2015.10.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review is focused on the chemistry of polynuclear halide complexes of Bi(III) (polyhalidebismuthates, or PHBs). It consists of three parts. The first one is dedicated to the known structural types of PHBs (discrete Bi(III) complexes, coordination polymers and heterometallic compounds), their features and occurrence. The second chapter briefly describes what can be called chemistry of PHBs (synthetic approaches by which they can be obtained, and some reactions they can be involved in). The final, third part is focused on the physical properties of PHBs reported recently, which would be of a special interest for the chemical community. (C) 2015 Elsevier B.V. All rights reserved.
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页码：1 / 21
页数：21
相关论文
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