Synthesis and characterization of microporous activated carbon from rubberwood by chemical activation with KOH

被引:30
作者
Thongpat, Wasutha [1 ]
Taweekun, Juntakan [2 ]
Maliwan, Kittinan [2 ]
机构
[1] Prince Songkla Univ, Energy Technol Program, Fac Engn, Hat Yai 90112, Songkhla, Thailand
[2] Prince Songkla Univ, Dept Mech & Mechatron Engn, Fac Engn, Hat Yai 90112, Songkhla, Thailand
关键词
Rubberwood; Activated carbon; Chemical activation; Microporous; KOH; RICE HUSK; ADSORPTION; PYROLYSIS; WOOD; PRECURSORS; SAWDUST; IRON;
D O I
10.1007/s42823-020-00224-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This research aims to study the effect of impregnation ratio and activation temperature on microporous development of activated carbon (AC). Rubberwood chips, which are wasted from home furnishing industry, were used as precursors for synthesized of activated carbon by chemical activation employing Potassium hydroxide (KOH) as activation agent. Rubberwood char was carbonized at 400 degrees C for 1 h under inert gas. In this experiment, the rubberwood chars were impregnated with KOH solution by 1:1-3 (char: KOH) impregnation ratio for 24 h, then the samples were activation at 600-800 degrees C. Surface area, pore volume, micropore volume, pore size distribution, adsorption isotherm and porous structure were analyzed in this experiment to identify the properties of derived activated carbon. According to the investigation, the activated carbon, activated at 800 degrees C with impregnation ratio of 1:3, demonstrated the highest surface area, pore volume and micropore volume as 1491.75 m(2)/g, 0.6777 cm(3)/g, and 0.5813 cm(3)/g, respectively. Its average pore size was 1.82 nm and it also showed type I adsorption isotherm which indicates as microporous solid.
引用
收藏
页码:1079 / 1088
页数:10
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