Synthesis and properties of novel unsymmetrical donor molecules containing p-acetoxy- or p-hydroxyphenyl units

被引：3

作者：

Kaboub, Lakhemici ^{[1
]}

Fradj, Slimane ^{[1
]}

Gouasmia, Abdelkrim ^{[1
]}

机构：

[1] Univ Tebessa, Dept Chim, Lab Mat Organ & Heterochim, Tebessa 12000, Algeria

来源：

MOLECULES | 2006年 / 11卷 / 10期

关键词：

tetratiafulvalene; voltammetry; organic materials; conductivity; degree of charge transfer;

D O I：

10.3390/11100776

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

We report the synthesis and properties of eight new tetrathiafulvalene (TTF) derivatives containing two different functionalities, prepared with the aim of obtaining stable organic materials. The four acetoxyphenyl- and four hydroxyphenyl TTFs were synthesized via Wittig-type condensations. The electrochemical properties of these redox-active molecules were studied by cyclic voltammetry. Charge transfer complexes with tetracyanoquinodimethane (TCNQ) were prepared by chemical redox reactions. The complexes have been proven to give conducting materials. The UV-VlS and IR spectra of the TCNQ salts were recorded and used to characterize and estimate the degree of charge transfer of these complexes.

引用

页码：776 / 785

页数：10

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