CTAB aggregation in aqueous solutions of ammonium based ionic liquids; conductimetric studies

被引：107
作者：
Modaressi, Ali
Sifaoui, Hocine
Grzesiak, Beata
Solimando, Roland
Domanska, Urszula
Rogalski, Marek
机构：
[1] Univ Metz, Lab Chim & Applicat, F-57078 Metz 03, France
[2] USTHB, Fac Chim, Lab Thermodynam & Modelisat Mol, Algiers, Algeria
[3] Warsaw Univ Technol, Div Phys Chem, PL-00664 Warsaw, Poland
[4] Inst Natl Polytech Lorraine, Ecole Natl Super Ind Chim, Lab Thermodynam Milieux Polyphases, F-54001 Nancy, France
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2007年 / 296卷 / 1-3期
关键词：
ionic liquids; micelles; surfactants; critical micelle concentration; electrical conductivity;
D O I：
10.1016/j.colsurfa.2006.09.031
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electrical conductivity/concentration data of aqueous solutions of n-hexadecyl-trimethylammonium bromide (CTAB), an cationic surfactant, with two ammonium based ionic liquids propyl-(2-hydroxyethyl)-dimethyl- ammonium bromide, (C3Br), butyl-(2-hydroxyethyl)-dimethylammonium bromide, (C4Br) of high melting points (> 373 K) were determined in the temperature range 298.15-328.15 K. These data were used to determining the critical micelle concentration (CMC) in function of concentration and temperature. The two ionic liquids and the surfactant have the same anion and the ammonium based cation. The influence of ionic liquids on the micellisation process of the CTAB is discussed. (c) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：104 / 108
页数：5
相关论文
共 27 条
[1]  
ALGREM M, 1983, J COLLOID INTERF SCI, V91, P256
[2]   Characterizing ionic liquids on the basis of multiple solvation interactions [J].
Anderson, JL ;
Ding, J ;
Welton, T ;
Armstrong, DW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14247-14254
[3]   Surfactant solvation effects and micelle formation in ionic liquids [J].
Anderson, JL ;
Pino, V ;
Hagberg, EC ;
Sheares, VV ;
Armstrong, DW .
CHEMICAL COMMUNICATIONS, 2003, (19) :2444-2445
[4]  
Attwood D., 1983, SURFACTANT SYSTEMS T, V1st, DOI DOI 10.1007/978-94-009-5775-6
[5]   Spectrophotometric and conductimetric determination of the critical micellar concentration of sodium dodecyl sulfate and cetyltrimethylammonium bromide micellar systems modified by alcohols and salts [J].
Benito, I ;
Garcia, MA ;
Monge, C ;
Saz, JM ;
Marina, ML .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1997, 125 (2-3) :221-224
[6]   Ionic liquids as stationary phase solvents for methylated cyclodextrins in gas chromatography [J].
Berthod, A ;
He, L ;
Armstrong, DW .
CHROMATOGRAPHIA, 2001, 53 (1-2) :63-68
[7]   Ionic liquids as modulators of the critical micelle concentration of sodium dodecyl sulfate [J].
Beyaz, A ;
Oh, WS ;
Reddy, VP .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2004, 35 (02) :119-124
[8]   High-pressure phase behavior of ionic liquid/CO2 systems [J].
Blanchard, LA ;
Gu, ZY ;
Brennecke, JF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (12) :2437-2444
[9]   THE EFFECT OF SALTS ON THE CRITICAL CONCENTRATION FOR THE FORMATION OF MICELLES IN COLLOIDAL ELECTROLYTES [J].
CORRIN, ML ;
HARKINS, WD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (03) :683-688
[10]   OSMOTIC COEFFICIENTS OF ALKYLTRIMETHYLAMMONIUM BROMIDES IN WATER AND IN AQUEOUS SODIUM-BROMIDE SOLUTIONS AT 55-DEGREES-C [J].
DEARDEN, LV ;
WOOLLEY, EM .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (09) :2404-2408
123