[μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0)

被引：1

作者：

bin Shawkataly, Omar ^{[1
]}

Khan, Imthyaz Ahmed ^{[1
]}

Yeap, Chin Sing ^{[2
]}

Fun, Hoong-Kun ^{[2
]}

机构：

[1] Univ Sains Malaysia, Sch Distance Educ, Chem Sci Programme, George Town 11800, Malaysia

[2] Univ Sains Malaysia, Xray Crystallog Unit, Sch Phys, George Town 11800, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

LIGAND-SUBSTITUTED DERIVATIVES; X-RAY STRUCTURES; CLUSTER CHEMISTRY; STEREOCHEMISTRY; P(OCH2CF3)3; COMPLEXES; PPH(OME)2; RU3(CO)12; OS3(CO)12;

D O I：

10.1107/S1600536809046704

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title triangulo-triruthenium compound, [Ru-3(C21H21As)(C25H22P2)(CO)(9)], the bis(diphenylphosphino) methane ligand bridges an Ru-Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru-3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of 87.36 (10), 81.96 (10) and 73.37 (11)degrees with each other. The dihedral angles between the two phenyl rings are 88.08 (12) and 80.15 (10)degrees for the two diphenylphosphino groups. In the crystal packing, the molecules are linked together as dimers via intermolecular C-H center dot center dot center dot O hydrogen bonds. These dimers are stacked down b axis. Intermolecular C-H center dot center dot center dot pi and pi-pi interactions [centroid-centroid distance = 3.6383 (13) angstrom] further stabilize the crystal structure.

引用

页码：M1622 / U1094

页数：18

共 13 条

[1] Tris(1-naphthyl)arsine chloroform solvate
bin Shawkataly, Omar
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2772 - U986
[2] Tris(2-methoxyphenyl)phosphine
bin Shawkataly, Omar
Pankhi, Mohd Aslam A.
Khan, Imthyaz Ahmed
Yeap, Chin Sing
Fun, Hoong-Kun
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : 01525 - U2042
[3] CLUSTER CHEMISTRY .17. RADICAL ION INITIATED SYNTHESES OF RUTHENIUM CLUSTER CARBONYLS CONTAINING TERTIARY PHOSPHINES, PHOSPHITES, ARSINES, SBPH3 OR ISOCYANIDES
BRUCE, MI
MATISONS, JG
NICHOLSON, BK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 247 (03) : 321 - 343
[4] CLUSTER CHEMISTRY .57. STEREOCHEMISTRY OF GROUP 15 LIGAND-SUBSTITUTED DERIVATIVES OF RU3(CO)12, OS3(CO)12 .C. X-RAY STRUCTURES OF RU3(CO)9(L)3 (L = PME2(CH2PH), PME2PH, ASME2PH, PPH(OME)2, P(OET)3, AND P(OCH2CF3)3) AND OS3(CO)9(PPH3)3
BRUCE, MI
LIDDELL, MJ
BINSHAWKATALY, O
HUGHES, CA
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 347 (1-2) : 207 - 235
[5] CLUSTER CHEMISTRY .56. STEREOCHEMISTRY OF GROUP 15 LIGAND-SUBSTITUTED DERIVATIVES OF RU3(CO)12, OS3(CO)12 .B. X-RAY STRUCTURES OF 6 COMPLEXES M3(CO)10(L)2 (M = RU, L = PPH3, PPH(OME)2, AND P(OCH2CF3)3 - M = OS, L = PPH3, PPH(OME)2 AND P(OME)3)
BRUCE, MI
LIDDELL, MJ
HUGHES, CA
PATRICK, JM
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 347 (1-2) : 181 - 205
[6] CLUSTER CHEMISTRY .35. REACTIONS OF SOME RUTHENIUM CLUSTER COMPLEXES WITH HYDROGEN - CLEAVAGE OF ELEMENT CARBON BONDS
BRUCE, MI
BINSHAWKATALY, O
WILLIAMS, ML
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 287 (01) : 127 - 131
[7] Bruker, 2005, APEX2 SAINT SADABS
[8] A NITROGEN-GAS-STREAM CRYOSTAT FOR GENERAL X-RAY-DIFFRACTION STUDIES
COSIER, J
GLAZER, AM
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (02) : 105 - 107
[9] SHAWKATALY O, 2006, ACTA CRYSTALLOGR E, V62, pM168
[10] Shawkataly O. B., 1998, POLYHEDRON, V17, P1211

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