The first bis(phosphine) monoxide (BPMO) complexes of copper(I)

被引：21
|
作者：
Saravanabharathi, D [1 ]
Nethaji, M [1 ]
Samuelson, AG [1 ]
机构：
[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
来源：
POLYHEDRON | 2002年 / 21卷 / 27-28期
关键词：
bis(phosphine) monoxides; Cu(I); chelates; NMR; electrochemistry; hard-soft acids and bases;
D O I：
10.1016/S0277-5387(02)01275-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Copper(l) complexes of bis(phosphine) monoxide ligands, bis(diphenylphosphino)ethane monoxide (dppeo) and bis(diphenylphosphino)methane monoxide (dppmo) have been prepared and characterized. One of the complexes with dppeo was characterized by X-ray crystal structure analysis confirming Cu(I) coordination to hard and soft donors. The stability of these complexes in solution was probed via spectroscopic and electrochemical studies. Copper(I) is more readily oxidized in the presence of the hard 0 donor ligands. In solution, they readily exchange the hard donor O, for soft ligands. Although copper(l) prefers soft ligands and is more stable towards oxidation in their presence, it coordinates to hard donors when there is electrostatic or an entropy driven advantage. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2793 / 2800
页数：8
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