Antibacterial Activities and UV Protection of the in Situ Synthesized Titanium Oxide Nanoparticles on Cotton Fabrics

被引:111
作者
El-Naggar, Mehrez E. [1 ]
Shaheen, Th. I. [1 ]
Zaghloul, S. [1 ]
El-Rafie, M. H. [1 ]
Hebeish, A. [1 ]
机构
[1] Natl Res Ctr, Text Res Div, Scopus Affiliat ID 60014618,33 El Bohouth St Dokk, Cairo, Egypt
关键词
SILVER NANOPARTICLES; HYDROTHERMAL SYNTHESIS; CELLULOSE FIBERS; TIO2; DIOXIDE; ANATASE; HYPOPHOSPHITE; TEXTILE; ACID;
D O I
10.1021/acs.iecr.5b04315
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In situ synthesis of titanium oxide nanoparticles (TiO(2)NPs) on cotton fabrics was innovatively studied. The synthesis involved the use of titanium isopropoxide (TIP) as a source of titanium hydroxide and urea nitrate as a peptizing agent responsible for conversion of titanium hydroxide to TiO(2)NPs. Characterization of TiO,NPs was performed using SEMEDX, XRD, FTIR, TEM, particle size analyzer, and zeta potential. The results obtained signify the following features. TiO(2)NPs are deposited in the form of coating on the surface of cotton fibers. They are composed of aggregated nanoparticles with an average size dimension that does not exceed 50 nm. On the other hand, TiO(2)NPs-loaded cotton fabrics exhibit a bacterial reduction of more than 95%, which is sustainable even after 20 washing cycles; the bacterial reduction increases by increasing the urea nitrate concentration used in the synthesis of TiO(2)NPs. Cotton fabrics coated with TiO(2)NPs display excellent UV protection before and after washing.
引用
收藏
页码:2661 / +
页数:8
相关论文
共 42 条
  • [1] Antibacterial property and characterization of cotton fabric treated with chitosan/AgCl-TiO2 colloid
    Arain, Rabia Almas
    Khatri, Zeeshan
    Memon, Muhammad Hanif
    Kim, Ick-Soo
    [J]. CARBOHYDRATE POLYMERS, 2013, 96 (01) : 326 - 331
  • [2] Surface functionalization of cellulose fibers with titanium dioxide nanoparticles and their combined bactericidal activities
    Daoud, WA
    Xin, JH
    Zhang, YH
    [J]. SURFACE SCIENCE, 2005, 599 (1-3) : 69 - 75
  • [3] Nucleation and growth of anatase crystallites on cotton fabrics at low temperatures
    Daoud, WA
    Xin, JH
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (05) : 953 - 955
  • [4] Bio-synthesis and applications of silver nanoparticles onto cotton fabrics
    El-Rafie, M. H.
    Shaheen, Th I.
    Mohamed, A. A.
    Hebeish, A.
    [J]. CARBOHYDRATE POLYMERS, 2012, 90 (02) : 915 - 920
  • [5] Environmental synthesis of silver nanoparticles using hydroxypropyl starch and their characterization
    El-Rafie, M. H.
    El-Naggar, M. E.
    Ramadan, M. A.
    Fouda, Moustafa M. G.
    Al-Deyab, Salem S.
    Hebeish, A.
    [J]. CARBOHYDRATE POLYMERS, 2011, 86 (02) : 630 - 635
  • [6] Antimicrobial effect of silver nanoparticles produced by fungal process on cotton fabrics
    El-Rafie, M. H.
    Mohamed, A. A.
    Shaheen, Th. I.
    Hebeish, A.
    [J]. CARBOHYDRATE POLYMERS, 2010, 80 (03) : 779 - 782
  • [7] The sol-gel synthesis of cotton/TiO2 composites and their antibacterial properties
    Galkina, O. L.
    Sycheva, A.
    Blagodatskiy, A.
    Kaptay, G.
    Katanaev, V. L.
    Seisenbaeva, G. A.
    Kessler, V. G.
    Agafonov, A. V.
    [J]. SURFACE & COATINGS TECHNOLOGY, 2014, 253 : 171 - 179
  • [8] Sodium hypophosphite and nano TiO2 inorganic catalysts along with citric acid on textile producing multi-functional properties
    Hashemikia, S.
    Montazer, M.
    [J]. APPLIED CATALYSIS A-GENERAL, 2012, 417 : 200 - 208
  • [9] Nanosized Carbamoylethylated Cellulose as Novel Precursor for Preparation of Metal Nanoparticles
    Hebeish, A.
    Farag, S.
    Sharaf, S.
    Shaheen, Th. I.
    [J]. FIBERS AND POLYMERS, 2015, 16 (02) : 276 - 284
  • [10] Development of improved nanosilver-based antibacterial textiles via synthesis of versatile chemically modified cotton fabrics
    Hebeish, A.
    El-Shafei, A.
    Sharaf, S.
    Zaghloul, S.
    [J]. CARBOHYDRATE POLYMERS, 2014, 113 : 455 - 462