Conformation-Driven Self-Assembly: From a 1D Metal-Organic Polymer to an Infinite Double Nanotube

被引：0
|
作者：
Xue, Hui [1 ]
Cao, Junze [1 ]
Zhao, Liang [1 ]
Hao, Haigang [1 ]
Hong, Maochun [2 ]
机构：
[1] Inner Mongolia Univ, Sch Chem & Chem Engn, Inner Mongolia Key Lab Chem & Phys Rare Earth Mat, Hohhot 010021, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
ACS OMEGA | 2019年 / 4卷 / 06期
基金：
中国国家自然科学基金;
关键词：
COORDINATION CAGES; GUEST; INTERCONVERSION; METALLACYCLES; METALLOCAGES; FRAMEWORKS; LIGANDS; ANIONS;
D O I：
10.1021/acsomega.9b01344
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal-organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a syn-conformation of ligands is a thermodynamically favored stable product than a one-dimensional polymer. To the best of our knowledge, this is the first example of the infinite metal-organic double nanotube. In addition, a discrete M6L8-type cage has also been in situ self-assembled from rationally selected building blocks.
引用
收藏
页码：10755 / 10760
页数：6
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