Radiation-induced phase transformations in MgAl2O4 spinel

被引:23
作者
Yu, N [1 ]
Devanathan, R [1 ]
Sickafus, KE [1 ]
Nastasi, M [1 ]
机构
[1] TEXAS INSTRUMENTS INC,SEMICOND PROC & DEVICE CTR,DALLAS,TX 75243
关键词
D O I
10.1557/JMR.1997.0243
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ion-irradiation was observed to transform MgAl2O4 spinel first to a metastable crystalline phase and then to an amorphous phase at cryogenic temperatures. Elastic stiffening of 15% occurred upon formation of the metastable crystalline phase. A second transformation from the metastable crystalline spinel to an amorphous state was accompanied by elastic softening of 25% relative to unirradiated spinel. This phase transformation behavior in spinel appears to be different from that in intermetallic compounds where only elastic softening associated with radiation damage accumulation is observed. A two-stage radiation damage model is proposed to explain the observed phase transformations.
引用
收藏
页码:1766 / 1770
页数:5
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[31]   CHARACTERIZATION AND SINTERING OF REACTIVE MGAL2O4 SPINEL [J].
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