Optically-detected magnetic resonance of spin-paired complexes emitting in the 2.3 eV spectral region in Mg-doped GaN

被引:2
作者
Aliev, G. N.
Zeng, S.
Bingham, S. J.
Wolverson, D. [1 ]
Davies, J. J.
Wang, T.
Parbrook, P. J.
机构
[1] Univ Bath, Dept Phys, Bath BA2 7AY, Avon, England
[2] Univ Sheffield, Dept Elect Engn, Sheffield, S Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1103/PhysRevB.74.235205
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Optically-detected magnetic resonance (ODMR) experiments on magnesium-doped GaN produced by metal-organic vapor phase epitaxy show a group of strong signals with large linewidths (in excess of 0.15 Tesla) obtained when monitoring photoluminescence in the region between 5000 A and 6200 A (2.5 eV to 2.0 eV). The signals depend upon the magnesium concentration and are particularly strong in as-grown material. The behavior of the spectrum for different directions of the applied magnetic field and for three well separated microwave frequencies is well described by the spin Hamiltonian for a coupled pair of centers, each with spins of S=1/2. The large ODMR linewidths are ascribed to hyperfine interactions with gallium nuclei, leading to a model in which this broad green-yellow photoluminescence band is due to a recombination process that involves magnesium acceptors closely paired with donor centers which contain interstitial gallium ions. Annealing is presumed to dissociate these pairs and thus to provide an activation process for the magnesium acceptors.
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页数:9
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