Ruthenium(II) complexes of some simple classic amine ligands

被引：1

作者：

Reeves, GorDan T. ^{[1
]}

Addison, Anthony W. ^{[2
]}

Zeller, Matthias ^{[3
]}

机构：

[1] Fairleigh Dickinson Univ, Dept Chem & Pharmaceut Sci, Madison, NJ 07940 USA

[2] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA

[3] Youngstown State Univ, STaRBURSTT CyberInstrumentat Consortium, Dept Chem, Youngstown, OH 44555 USA

来源：

INORGANICA CHIMICA ACTA | 2015年 / 432卷

关键词：

Ruthenium; Amine; Diimine; X-ray structure; X-RAY STRUCTURE; REDOX POTENTIALS; CHEMISTRY; TRIS(2-PYRIDYLMETHYL)AMINE; FUNCTIONALIZATION; IMIDAZOLE; OXIDATION; SERIES; STATES;

D O I：

10.1016/j.ica.2015.04.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new Ru(II) complexes of tris(2-aminoethyl)amine (Tren) and diethylenetriamine (Dien) have been prepared using Ru(PPh3)(3)Cl-2 and [(CH3)(4)N](2)[Ru(Phen)Cl-4] (1) as starting materials. The reaction of Tren or Dien with Ru(PPh3)(3)Cl-2 leads to the formation of either the [Ru(Tren)(PPh3)Cl]Cl (2) or the Ru(Dien)(PPh3)Cl-2 (4) complex, of which the latter then reacts further with a heterocyclic diimine (N-N) ligand to yield [Ru(Dien)(PPh3)(N-N)]Cl-2. Addition of Tren or Dien to solutions of the [(CH3)(4)N](2)[Ru(Phen)Cl-4] complex replaces the coordinated chlorides with the N-donor ligand, forming [Ru(Tren)Phen](ClO4)(2) (3) and [Ru(Dien)(Phen)Cl]Cl (5) respectively. Redox chemistry shows single-electron Ru(II) --> Ru(III) oxidations over a wide range of potentials. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：185 / 191

页数：7

共 36 条

[1] On the relative magnitudes of cis and trans influences in metal complexes [J].

Anderson, KM ;

Orpen, AG .

CHEMICAL COMMUNICATIONS, 2001, (24) :2682-2683

[2]

[Anonymous], BRUK ADV XRAY SOL SA

[3]

[Anonymous], BRUK ADV XRAY SOL SH

[4] Chemistry of ruthenium with some phenolic ligands: synthesis, structure and redox properties [J].

Basuli, F ;

Das, AK ;

Mostafa, G ;

Peng, SM ;

Bhattacharya, S .

POLYHEDRON, 2000, 19 (14) :1663-1672

[5] RUTHENIUM COMPLEXES CONTAINING TERTIARY PHOSPHINES AND IMIDAZOLE OR 2,2'-BIPYRIDINE LIGANDS [J].

BATISTA, AA ;

POLATO, EA ;

QUEIROZ, SL ;

NASCIMENTO, OR ;

JAMES, BR ;

RETTIG, SJ .

INORGANICA CHIMICA ACTA, 1995, 230 (1-2) :111-117

[6] Electrochemical and spectroscopic studies on RuCl2(PPh3)2(N)2 and RUCl2(PPh3)2(N-N) complexes (N = pyridine derivatives and N-N = phenanthroline or bipyridine derivatives).: X-ray structure of RuCl2(PPh3)2(phen) [J].

Batista, AA ;

Santiago, MO ;

Donnici, CL ;

Moreira, IS ;

Healy, PC ;

Berners-Price, SJ ;

Queiroz, SL .

POLYHEDRON, 2001, 20 (17) :2123-2128

[7]

CENINI S, 1982, J MOL CATAL, V15, P297, DOI 10.1016/0304-5102(82)80023-0

[8]

Chiou Y.-M., 1995, AM CHEM SOC, V115, P3999

[9] Ruthenium phosphine/diimine complexes: Syntheses, characterization, reactivity with carbon monoxide, and catalytic hydrogenation of ketones [J].

de Araujo, MP ;

de Figueiredo, AT ;

Bogado, AL ;

Von Poelhsitz, G ;

Ellena, J ;

Castellano, EE ;

Donnici, CL ;

Comasseto, JV ;

Batista, AA .

ORGANOMETALLICS, 2005, 24 (25) :6159-6168

[10] 3-Rhoda-1,2-diazacyclopentanes: A Series of Novel Metallacycle Complexes Derived From C-N Functionalization of Ethylene [J].

Drover, Marcus W. ;

Beh, Daniel W. ;

Kennepohl, Pierre ;

Love, Jennifer A. .

CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (41) :13345-13355

← 1 2 3 4 →