Suppressed tanδ and enhanced Qm in KCT and Ni2O3 co-modified [(K0.43Na0.57)0.94Li0.06] [(Nb0.94Sb0.06)0.95Ta0.05O3 lead-free piezoelectric ceramics

被引:24
作者
Zhang, Qingfeng [1 ]
Xu, Fang [1 ,2 ]
Yang, Ronghuizi [1 ]
Lu, Yinmei [1 ]
Li, Pai [1 ]
Shang, Xunzhong [1 ]
Zhou, Taosheng [1 ]
He, Yunbin [1 ]
机构
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Green Preparat & Applicat Funct Mat,Fac M, Wuhan 430062, Peoples R China
[2] JiangXi Univ Technol, Nanchang 330098, Peoples R China
基金
中国国家自然科学基金;
关键词
KNN-based lead-free piezoelectric ceramics; Enhanced mechanical quality factor; Low dielectric loss; High piezoelectric constant; High power transducers; FREE PIEZOCERAMICS; MICROSTRUCTURE;
D O I
10.1016/j.ceramint.2016.11.056
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Effects of K5.4Cu1.3Ta10O29 (KCT) doping on structural and electrical properties of 0.05 mol% Ni2O3 modified [(K0.43Na0.57)(0.94)Li-0.06][(Nb0.94Sb0.06)(0.95)Ta-0.95]O-3 (KNLNST) ceramics have been studied. It is found that the addition of suitable amount KCT can significantly enhance Q(m) and suppress land while virtually maintaining d(33) of the ceramics. The 0.2 mol% KCT added KNLNST +0.05 mol% Ni2O3 ceramic shows a high Q(m) (similar to 180) and a very low tan delta (0.82%), which are respectively nearly four times and a quarter of those of pure KNLNST +0.05 mol% Ni2O3 ceramic. Meanwhile, d(33) and k(p) of this ceramic maintain relatively high values (d(33)=287 pC/N, k(p)=46.2%). The dramatic change of Q(m) (tan delta) and virtual maintenance of d(33) (k(p)) are mainly attributed to the effects of Cu2+ and K+ in KCT, respectively. High Q(m) and d(33) but remarkably low tan delta indicates large potential of this ceramic for making high power transducer devices.
引用
收藏
页码:2537 / 2540
页数:4
相关论文
共 18 条
[1]  
[Anonymous], 1987, ANSIIEEE STANDARD NO
[2]   Microstructure and piezoelectric properties of 0.95(Na0.5K0.5)NbO3-0.05SrTiO3 ceramics [J].
Cho, Kyung-Hoon ;
Park, Hwi-Yeol ;
Ahn, Cheol-Woo ;
Nahm, Sahn ;
Uchino, Kenji ;
Park, Seung-Ho ;
Lee, Hyeung-Gyu ;
Lee, Hwack-Joo .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (06) :1946-1949
[3]  
Dai YJ, 2007, APPL PHYS LETT, V90, DOI 10.1063/1.2751607
[4]   High-Performance Small-Amount Fe2O3-Doped (K,Na) NbO3-Based Lead-Free Piezoceramics with Irregular Phase Evolution [J].
Guo, Jinming ;
Xu, Fang ;
Shang, Xunzhong ;
Lu, Yinmei ;
Li, Pai ;
Zhou, Taosheng ;
Zhang, Zaoli ;
He, Yunbin .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2016, 99 (07) :2341-2346
[5]   Dielectric and piezoelectric properties of Cu2+-doped alkali Niobates [J].
Hagh, N. Marandian ;
Kerman, K. ;
Jadidian, B. ;
Safari, A. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2009, 29 (11) :2325-2332
[6]   Temperature dependence on the piezoelectric property of (1-x)(Na0.5K0.5)NbO3-xLiNbO3 ceramics [J].
Higashide, Kazuhiko ;
Kakimoto, Ken-ichi ;
Ohsato, Hitoshi .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (13-15) :4107-4110
[7]   Enhancement of Qm, by co-doping of Li and Cu to potassium sodium niobate lead-free ceramics [J].
Li, Enzhu ;
Kakemoto, Hirofumi ;
Wada, Satoshi ;
Tsurumi, Takaaki .
IEEE TRANSACTIONS ON ULTRASONICS FERROELECTRICS AND FREQUENCY CONTROL, 2008, 55 (05) :980-987
[8]   (K, Na) NbO3-Based Lead-Free Piezoceramics: Fundamental Aspects, Processing Technologies, and Remaining Challenges [J].
Li, Jing-Feng ;
Wang, Ke ;
Zhu, Fang-Yuan ;
Cheng, Li-Qian ;
Yao, Fang-Zhou .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (12) :3677-3696
[9]   Synthesis and characterization of (K0.5Na0.5)(Nb0.7Ta0.3)O3 piezoelectric ceramics sintered with sintering aid K5.4Cu1.3Ta10O29 [J].
Matsubara, M ;
Yamaguchi, T ;
Kikuta, K ;
Hirano, S .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (9A) :6618-6623
[10]   Highly enhanced mechanical quality factor in lead-free (K0.5Na0.5)NbO3 piezoelectric ceramics by co-doping with K5.4Cu1.3Ta10O29 and CuO [J].
Park, Beom Chul ;
Hong, In Ki ;
Jang, Hyun Deok ;
Tran, Vu Diem Ngoc ;
Tai, Weon Pil ;
Lee, Jae-Shin .
MATERIALS LETTERS, 2010, 64 (14) :1577-1579