Role of specific distorted metal complexes in exciton self-trapping for hybrid metal halides

被引:9
作者
Gautier, Romain [1 ]
Clerac, Rodolphe [2 ]
Paris, Michael [1 ]
Massuyeau, Florian [1 ]
机构
[1] Univ Nantes, CNRS, Inst Mat Jean Eauxel, IMN, F-44000 Nantes, France
[2] Univ Bordeaux, CNRS, Ctr Rech Paul Pascal, UMR 5031, F-33600 Pessac, France
关键词
LUMINESCENCE; PEROVSKITES; EMISSION; CRYSTAL;
D O I
10.1039/d0cc04778c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A methodology enabling the discovery of hybrid metal halide phosphors through the selection of structural networks, which exhibit a specific distorted environment of the metal ions associated with the self-trapping of excitons, is proposed. This approach is demonstrated with the synthesis of an efficient near-UV emitting hybrid cadmium halide phosphor.
引用
收藏
页码:10139 / 10142
页数:4
相关论文
共 35 条
[21]   Organic-Inorganic Perovskites: Structural Versatility for Functional Materials Design [J].
Saparov, Bayrammurad ;
Mitzi, David B. .
CHEMICAL REVIEWS, 2016, 116 (07) :4558-4596
[22]   Lead-Free Tin(IV)-Based Organic-Inorganic Metal Halide Hybrids with Excellent Stability and Blue-Broadband Emission [J].
Song, Gaomin ;
Li, Mingze ;
Yang, Yi ;
Liang, Fei ;
Huang, Qian ;
Liu, Xiaomeng ;
Gong, Pifu ;
Xia, Zhiguo ;
Lin, Zheshuai .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2020, 11 (05) :1808-1813
[23]  
Song K.S., 1993, SELF TRAPPED EXCITON
[24]   Luminescent perovskites: recent advances in theory and experiments [J].
Song, Zhen ;
Zhao, Jing ;
Liu, Quanlin .
INORGANIC CHEMISTRY FRONTIERS, 2019, 6 (11) :2969-3011
[25]   (4NPEA)2PbI4 (4NPEA=4-Nitrophenylethylammonium): Structural, NMR, and Optical Properties of a 3 x 3 Corrugated 2D Hybrid Perovskite [J].
Tremblay, Marie-Helene ;
Thouin, Felix ;
Leisen, Johannes ;
Bacsa, John ;
Kandada, Ajay Ram Srimath ;
Hoffman, Justin M. ;
Kanatzidis, Mercouri G. ;
Mohite, Aditya D. ;
Silva, Carlos ;
Barlow, Stephen ;
Marder, Seth R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (11) :4521-4525
[26]   Atomistic Mechanism of Broadband Emission in Metal Halide Perovskites [J].
Wang, Xiaoming ;
Meng, Weiwei ;
Liao, Weiqiang ;
Wang, Jianbo ;
Xiong, Ren-Gen ;
Yan, Yanfa .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2019, 10 (03) :501-506
[27]   A One-Dimensional Organic Lead Chloride Hybrid with Excitation-Dependent Broadband Emissions [J].
Wu, Guanhong ;
Zhou, Chenkun ;
Ming, Wenmei ;
Han, Dan ;
Chen, Shiyou ;
Yang, Dong ;
Besara, Tiglet ;
Neu, Jennifer ;
Siegrist, Theo ;
Du, Mao-Hua ;
Ma, Biwu ;
Dong, Angang .
ACS ENERGY LETTERS, 2018, 3 (06) :1443-1449
[28]   Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic-Inorganic Perovskite (C6H11NH3)2PbBr4 [J].
Yangui, A. ;
Garrot, D. ;
Lauret, J. S. ;
Lusson, A. ;
Bouchez, G. ;
Deleporte, E. ;
Pillet, S. ;
Bendeif, E. E. ;
Castro, M. ;
Triki, S. ;
Abid, Y. ;
Boukheddaden, K. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (41) :23638-23647
[29]   Hybrid Organic-Inorganic Halides (C5H7N2)2MBr4 (M = Hg, Zn) with High Color Rendering Index and High-Efficiency White-Light Emission [J].
Yangui, Aymen ;
Roccanova, Rachel ;
McWhorter, Timothy M. ;
Wu, Yuntao ;
Du, Mao-Hua ;
Saparov, Bayrammurad .
CHEMISTRY OF MATERIALS, 2019, 31 (08) :2983-2991
[30]   Doped Lead Halide White Phosphors for Very High Efficiency and Ultra-High Color Rendering [J].
Yuan, Hailong ;
Massuyeau, Florian ;
Gautier, Nicolas ;
Kama, Antoine Blaise ;
Faulques, Eric ;
Chen, Fei ;
Shen, Qiang ;
Zhang, Lianmeng ;
Paris, Michael ;
Gautier, Romain .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (07) :2802-2807