A study of oxidation behavior of AlTiN-and AlCrN-based multilayer coatings

被引：47
作者：
Xiao, Baijun [1 ]
Li, Haixu [1 ]
Mei, Haijuan [1 ]
Dai, Wei [1 ]
Zuo, Fei [1 ]
Wu, Zhengtao [1 ]
Wang, Qimin [1 ]
机构：
[1] Guangdong Univ Technol, Sch Electromech Engn, Guangzhou 510006, Guangdong, Peoples R China
来源：
SURFACE & COATINGS TECHNOLOGY | 2018年 / 333卷
关键词：
AlCrN-and AlTiN-based multilayer; Thermogravimetric analysis; High temperature oxidation; Oxidation mechanism; HARD COATINGS; MECHANICAL-PROPERTIES; CUTTING PERFORMANCE; THERMAL-PROPERTIES; THIN-FILMS; TEMPERATURE; RESISTANCE; MICROSTRUCTURE; EVAPORATION; DEPOSITION;
D O I：
10.1016/j.surfcoat.2017.10.078
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
In this work, AlTiN/TiSiN and AlCrN/TiSiN multilayer coatings were deposited by arc ion plating on Al2O3 and cemented carbide substrates. The oxidation resistances of the coatings were studied under isothermal conditions up to 1000 degrees C. The oxidation behaviors of the multilayer coatings were studied by means of cross-sectional SEM (X-SEM), energy dispersive X-ray (EDX) maps analysis, X-ray diffraction (XRD) and EDX line-scanning after oxidation at 800 degrees C, 900 degrees C and 1000 degrees C in air for 2 h. The oxide scale formed on the surface region of the AlTiN/TiSiN coating illustrates a mixture of porous (Al, Ti)-Oxide scale. On the contrary, the oxide scale of the AlCrN/TiSiN coating mainly consists of a mixed (Ti, Al)-oxide scale outside layer and a dense (Al, Cr)(2)O-3 inner layer. During the isothermal oxidation, the AlCrN/TiSiN coating exhibits lower weight increment. The oxidation result shows that the AlCrN/TiSiN multilayer coating exhibits more considerable oxidation resistance than that of the AlTiN/TiSiN coating. The formation of a dense protective mixed (Al, Cr)-oxide scale beneath the TiSiN layer acts as a barrier layer, blocking the outward diffusion of the Al, Ti and Cr atoms and retarding inward diffusion of oxygen into the AlCrN/TiSiN coating.
引用
收藏
页码：229 / 237
页数：9
相关论文
共 34 条
[1]   Deposition and characterization of TiAlN/Si3N4 superhard nanocomposite coatings prepared by reactive direct current unbalanced magnetron sputtering [J].
Barshilia, Harish C. ;
Deepthi, B. ;
Rajam, K. S. .
VACUUM, 2006, 81 (04) :479-488
[2]   Wear behavior of adaptive nano-multilayered AlTiN/MexN PVD coatings during machining of aerospace alloys [J].
Biksa, A. ;
Yamamoto, K. ;
Dosbaeva, G. ;
Veldhuis, S. C. ;
Fox-Rabinovich, G. S. ;
Elfizy, A. ;
Wagg, T. ;
Shuster, L. S. .
TRIBOLOGY INTERNATIONAL, 2010, 43 (08) :1491-1499
[3]   DC-MSIP/HPPMS (Cr,Al,V)N and (Cr,Al,W)N thin films for high-temperature friction reduction [J].
Bobzin, K. ;
Bagcivan, N. ;
Ewering, M. ;
Brugnara, R. H. ;
Theiss, S. .
SURFACE & COATINGS TECHNOLOGY, 2011, 205 (8-9) :2887-2892
[4]   Effect of silicon content on PVD film mechanical properties and cutting performance of coated cemented carbide inserts [J].
Bouzakis, K. -D. ;
Bouzakis, E. ;
Kombogiannis, S. ;
Paraskevopoulou, R. ;
Skordaris, G. ;
Makrimallakis, S. ;
Katirtzoglou, G. ;
Pappa, M. ;
Gerardis, S. ;
M'Saoubi, R. ;
Andersson, J. M. .
SURFACE & COATINGS TECHNOLOGY, 2013, 237 :379-389
[5]   Magnetron sputtering of Cr(AI)N coatings:: Mechanical and tribological study [J].
Brizuela, M ;
Garcia-Luis, A ;
Braceras, I ;
Oñate, JI ;
Sánchez-López, JC ;
Martínez-Martínez, D ;
López-Cartes, C ;
Fernández, A .
SURFACE & COATINGS TECHNOLOGY, 2005, 200 (1-4) :192-197
[6]   Characteristics and performance of TiSiN/TiAlN multilayers coating synthesized by cathodic arc plasma evaporation [J].
Chang, Chi-Lung ;
Chen, Wei-Chih ;
Tsai, Pi-Chuen ;
Ho, Wei-Yu ;
Wang, Da-Yung .
SURFACE & COATINGS TECHNOLOGY, 2007, 202 (4-7) :987-992
[7]   High temperature oxidation resistance of multicomponent Cr-Ti-Al-Si-N coatings [J].
Chang, Yin-Yu ;
Hsiao, Chia-Yuan .
SURFACE & COATINGS TECHNOLOGY, 2009, 204 (6-7) :992-996
[8]   Effect of bilayer period on structure, mechanical and thermal properties of TiAlN/AlTiN multilayer coatings [J].
Chen, Li ;
Xu, Yu X. ;
Du, Yong ;
Liu, Yong .
THIN SOLID FILMS, 2015, 592 :207-214
[9]   Preparation and characterization of CrAlN/TiAlSiN nano-multilayers by cathodic vacuum arc [J].
Chen, Wanglin ;
Lin, Yue ;
Zheng, Jie ;
Zhang, Shihong ;
Liu, Shuyuan ;
Kwon, S. C. .
SURFACE & COATINGS TECHNOLOGY, 2015, 265 :205-211
[10]   Mechanical and structural properties of various alloyed TiAlN-based hard coatings [J].
Derflinger, VH ;
Schütze, A ;
Ante, M .
SURFACE & COATINGS TECHNOLOGY, 2006, 200 (16-17) :4693-4700
1234