Analysis of Gaseous Products of Plasma Electrolytic Oxidation of Aluminum

被引：2
|
作者：
Golovenko, V. A. [1 ]
Kalinichenko, O. A. [1 ]
Roenko, E. V. [1 ]
Gurevina, N. L. [1 ]
Snezhko, L. A. [1 ]
机构：
[1] Ukrainian State Univ Chem Technol, State Higher Educ Inst, UA-49005 Dnipro, Ukraine
来源：
SURFACE ENGINEERING AND APPLIED ELECTROCHEMISTRY | 2019年 / 55卷 / 02期
关键词：
aluminum; anodic gas consumption; anodic-spark oxidation; HYDROGEN GENERATION; MICROSTRUCTURE; MECHANISM; COATINGS; WATER;
D O I：
10.3103/S1068375519020108
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The measurements of the volume and density of the anodic gas evolved in anodic-spark oxidation showed that the ratio of hydrogen to oxygen is about 1.6-1.8 at current densities of 1000-3000 A m(-2). The fraction of anodic hydrogen is in the range of 1.17-1.38% among the total hydrogen released during the anodic-spark oxidation from both electrodes. Hypothetical reactions responsible for the appearance of hydrogen in the anodic gas are considered. It is shown that the oxide current output calculated in accordance with electrochemical regularities decreases with increasing current density, in the range of 11-18%. This is indicative of the enhancing role of thermochemical processes upon a higher intensity of sparks and an increase in their sizes.
引用
收藏
页码：191 / 196
页数：6
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