Copper-catalyzed Csp3-O cross-coupling of unactivated alkyl halides with organic peroxides

被引：11
|
作者：
Chen, Huan-Huan [1 ,2 ,3 ]
Wang, Guang-Zu [1 ,2 ,3 ]
Han, Jin [1 ,2 ,3 ]
Xu, Meng-Yu [1 ,2 ,3 ]
Zhao, Yong-Qiang [1 ,2 ,3 ]
Xu, Hua-Jian [1 ,2 ,3 ]
机构：
[1] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Anhui, Peoples R China
[2] Hefei Univ Technol, Sch Med Engn, Hefei 230009, Anhui, Peoples R China
[3] Key Lab Adv Funct Mat & Devices, Hefei 230009, Anhui, Peoples R China
来源：
TETRAHEDRON | 2014年 / 70卷 / 02期
基金：
中国国家自然科学基金;
关键词：
C-sp3-O coupling; Copper-catalyzed; Organic peroxides; Secondary alkyl halides; Aryl alkyl esters; C-H BONDS; CARBOXYLATES; ARTEMISININ; DERIVATIVES; ACTIVATION; LIGAND; ESTERS;
D O I：
10.1016/j.tet.2013.11.085
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient Cu-catalyzed C-sp3-O coupling of peroxides with haloalkanes is described. High yields of products were achieved under mild conditions. Significantly, in addition to primary alkyl halides, secondary alkyl halogenated hydrocarbons could also be applied to this system. The new reaction system could tolerate a wide range of organic peroxides. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：212 / 217
页数：6
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