Platinum nanoparticles supported on a bi-metal oxide grown carbon nanostructure as an ethanol electro-oxidation electrocatalyst

被引:11
作者
Divya, P. [1 ]
Ramaprabhu, S. [1 ]
机构
[1] Indian Inst Technol Madras, Dept Phys, NFMTC, AENL, Madras, Tamil Nadu, India
关键词
ELECTROCHEMICAL OXIDATION; ANODE CATALYSTS; NANOTUBES; RAMAN; PT/C; PALLADIUM; PT-CEO2/C;
D O I
10.1039/c3ta13070c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of inexpensive and highly active ethanol electro-oxidation electrocatalysts is a great challenge. Here, we report a novel material consisting of platinum dispersed on a bi-metal oxide grown carbon nanostructure as an ethanol electro-oxidation electrocatalyst. The carbon nanostructure has been synthesized by the catalytic chemical vapour deposition of acetylene precursor over Fe-Sn-O particles. Platinum (Pt) nanoparticles have been decorated on a bi-metal oxide grown carbon nanostructure (CNS-FSO) by the polyol reduction technique. The suitability of the electrocatalyst for ethanol electro-oxidation is examined by cyclic voltammetry and amperometry techniques. Pt supported on CNS-FSO exhibited a higher catalytic activity towards ethanol electro-oxidation in comparison to commercially available platinum on Vulcan XC-72 and platinum nanoparticles decorated functionalized multi walled carbon nanotubes. This superior activity can be attributed to the unique properties of CNS-FSO as well as the synergic effect between platinum and CNS-FSO.
引用
收藏
页码:13605 / 13611
页数:7
相关论文
共 50 条
  • [31] Palladium Nanoparticles Supported on Phosphorus-Doped Graphitic Carbon Nitride/Carbon Black Hybrids for Formic Acid Electro-Oxidation
    Yu, Duo
    Lu, Chenxi
    Yan, Zhiguo
    Yang, Xiaojun
    Yang, Wei
    Lv, Zaosheng
    Tian, Zhengfang
    Tian, Qifeng
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2021, 16 (10): : 1 - 15
  • [32] A Monolithic Carbon Foam-Supported Pd-Based Catalyst towards Ethanol Electro-Oxidation in Alkaline Media
    Li, Yinshi
    Lv, Jianhao
    He, Yaling
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (05) : F424 - F427
  • [33] Tin oxide as a promoter for copper@palladium nanoparticles on graphene sheets during ethanol electro-oxidation in NaOH solution
    Hameed, R. M. Abdel
    Fahim, Ahmed E.
    Allam, Nageh K.
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 297
  • [34] High performance of a carbon supported ternary PdIrNi catalyst for ethanol electro-oxidation in anion-exchange membrane direct ethanol fuel cells
    Shen, Shuiyun
    Zhao, T. S.
    Xu, Jianbo
    Li, Yinshi
    ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (04) : 1428 - 1433
  • [35] Galvanic Replacement-Mediated Synthesis of Ni-Supported Pd Nanoparticles with Strong Metal-Support Interaction for Methanol Electro-oxidation
    Lei, Hao
    Li, Xiaotong
    Sun, Changbin
    Zeng, Junrong
    Siwal, Samarjeet Singh
    Zhang, Qibo
    SMALL, 2019, 15 (11)
  • [36] Fabrication of Pt-CeO2 nanoparticles supported sulfonated reduced graphene oxide as an efficient electrocatalyst for ethanol oxidation
    Kakaei, Karim
    Rahimi, Aylar
    Husseindoost, Somayeh
    Hamidi, Milad
    Javan, Hakimeh
    Balavandi, Amin
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (06) : 3861 - 3869
  • [37] Electro-catalysis of carbon black or titanium sub-oxide supported Pd-Gd towards formic acid electro-oxidation
    He, Nan
    Qin, Chuanguang
    Wang, Rumin
    Ma, Shuhui
    Wang, Yi
    Qi, Tao
    RSC ADVANCES, 2016, 6 (73) : 68989 - 68996
  • [38] Fabrication of Ultrafine Amorphous Pd-Ni-P Nanoparticles Supported on Carbon Nanotubes as an Effective Catalyst for Electro-oxidation of Methanol
    Zhao, Ming
    Ji, Yuan
    Zhong, Ning
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2016, 11 (12): : 10488 - 10497
  • [39] Pt nanoparticles supported on porous sheath TiO2 wrapped carbon nanotubes for selective glycerol electro-oxidation into tartronate
    Guan, Chaohui
    Li, Jiefei
    Chen, Tao
    Lv, Liang
    Du, Junfeng
    Zhang, Shuai
    Wei, Hang
    Chu, Haibin
    JOURNAL OF MATERIALS CHEMISTRY A, 2025, 13 (10) : 7168 - 7175
  • [40] Highly active carbon supported ternary PdSnPtx (x=0.1-0.7) catalysts for ethanol electro-oxidation in alkaline and acid media
    Wang, Xiaoguang
    Zhu, Fuchun
    He, Yongwei
    Wang, Mei
    Zhang, Zhonghua
    Ma, Zizai
    Li, Ruixue
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 468 : 200 - 210