The surfactant sensitized analytical reaction of cerium(IV) with some triphenylformazan derivatives

Cationic surfactant, cetylpyridinium bromide (CPB), sensitizes the colour reaction of cerium(IV) with 1,3-o-hydroxyphenyl-5-phenylformazan(I), 1-m-hydroxyphenyl-3-o-hydroxyphenyl-5-phenylformazan(II) and 1-m-carboxyphenyl-3-o-hydroxyphenyl-5-phenylformazan(III). The formation of a soluble ternary complex of stoichiometric ratio 1: 1: 1 (Ce(IV)-R-CPB) is responsible for the observed enhancement in the molar absorptivity and Sandell sensitivity of the formed complex, when a surfactant is present. The ternary complex exhibits absorption maxima at 596, 571 and 607 nm (epsilon = 6.05 x 10(4), 6.28 x 10(4) and 8.06 x 10(4) L mol(-1) cm(-1)) using triphenylformazan derivatives 1, 11 and 111, respectively. Beer's law is obeyed between 0.15 and 2.5 mu g ml(-1), whereas, optimum concentration range applying Ringbom method is in the range 0.30-2.25 mu g ml(-1). Conditional formation constants in the presence and absence of CPB for Ce(IV) complexes have been calculated. The proposed method has been successfully applied to the analysis of magnesium-base cerium alloys and synthetic mixtures corresponding to various cerium alloys. (c) 2005 Elsevier B.V. All rights reserved.