Impacts of Ni-Co substitution on the structural, magnetic and dielectric properties of magnesium nano-ferrites fabricated by micro-emulsion method

被引:114
作者
Ali, Rajjab [1 ]
Mahmood, Azhar [1 ]
Khan, Muhammad Azhar [2 ]
Chughtai, Adeel Hussain [3 ]
Shahid, Muhammad [4 ]
Shakir, Imran [5 ]
Warsi, Muhammad Farooq [1 ]
机构
[1] Islamia Univ Bahawalpur, Dept Chem, Bahawalpur 63100, Pakistan
[2] Islamia Univ Bahawalpur, Dept Phys, Bahawalpur 63100, Pakistan
[3] Bahauddin Zakaryia Univ, Inst Chem Sci, Multan 6100, Pakistan
[4] Sungkyunkwan Univ, Dept Energy Sci, SKKU Adv Inst Nanotechnol, BK Phys Res Div 21,Inst Basic Sci, Suwon 440746, South Korea
[5] King Saud Univ, Coll Engn, Riyadh 11421, Saudi Arabia
关键词
Nano-ferrites; Magnetic properties; Dielectric properties; GHz frequency; CATION DISTRIBUTION; ELECTRICAL-PROPERTIES; MFE2O4; M; ZN; MG; NANOPARTICLES; BEHAVIOR; MGFE2O4; SYSTEM; COBALT;
D O I
10.1016/j.jallcom.2013.08.114
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Magnesium ferrite (MgFe2O4) nano-structures doped with Ni-Co at magnesium and iron sites respectively were fabricated by the micro-emulsion method and characterized by the X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM) and dielectric measurements. The analysis of XRD patterns confirm the single phase spinel structure and the crystallite size calculated by Scherer's formula lies in the range of 15-26 nm. The spectral studies elucidate the characteristic feature of spinel phase. The real and imaginary parts of dielectric constant and dielectric loss exhibit peaking behavior. The dielectric properties have been explained on the basis of Debye-type relaxation phenomenon in accordance with Koop's phenomenological theory. The increase in the tendency of saturation magnetization is consistent with the enhancement of crystallinity. The crystallite size is small enough to obtain considerable signal to noise ratio in the recording media. The optimized dielectric and magnetic parameters suggest that the material with composition Mg-0.6 Ni-0.4 Co-0.4 Fe1.6O4 may be used for applications in recording media and microwave devices. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:363 / 368
页数:6
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