Multiwalled carbon nanotube wrapped hydroxyapatite, convenient synthesis via microwave assisted solid state metathesis

被引：12

作者：

Safavi, Afsaneh ^{[1
,2
]}

Sorouri, Mohsen ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 71454, Iran

[2] Shiraz Univ, Nanotechnol Res Inst, Shiraz 71454, Iran

来源：

MATERIALS LETTERS | 2013年 / 91卷

关键词：

Carbon nanotubes; Hydroxyapatite; Solid state metathesis reaction; Microwave assisted synthesis; Nanocomposites; NANOCOMPOSITE;

D O I：

10.1016/j.matlet.2012.09.075

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A rapid and convenient method is described for carbon nanotube (CNT) wrapping by in-situ hydroxyapatite (HA) formation via microwave (MW) assisted solid state metathesis reaction (SSM). The straightforward, solventless process requires no polyelectrolyte modification of CNTs and provides a uniform structure. Electrochemical impedance spectroscopy (EIS) revealed the surprisingly better charge transfer for the synthesized composite in comparison with the pristine multiwalled carbon nanotube (MWCNT). The interactions with biomolecules as well as the high sorptivity of HA with improved electrical properties, make MWCNT wrapped HA nanohybrid a favorable electrochemical platform. The proposed composite is promising for sensor technology and bioelectronic devices. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：287 / 290

页数：4

共 15 条

[1] Synthesis and characterization of hydroxyapatite using carbon nanotubes as a nano-matrix [J].

Aryal, S ;

Bahadur, KCR ;

Dharmaraj, N ;

Kim, KW ;

Kim, HY .

SCRIPTA MATERIALIA, 2006, 54 (02) :131-135

[2] Charge transfer effects in acid treated single-wall carbon nanotubes [J].

Barros, EB ;

Souza, AG ;

Lemos, V ;

Mendes, J ;

Fagan, SB ;

Herbst, MH ;

Rosolen, JM ;

Luengo, CA ;

Huber, JG .

CARBON, 2005, 43 (12) :2495-2500

[3] Carbon nanotube-hydroxyapatite nanocomposite for DNA complexation [J].

Bhattarai, Shanta Raj ;

Aryal, Santosh ;

C., Remant Bahadur K. ;

Bhattarai, Narayan ;

Hwang, Pyong Han ;

Yi, Ho Keun ;

Kim, Hak Yong .

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2008, 28 (01) :64-69

[4]

Boivin Georges., 2007, MEDICOGRAPHIA, V29, P126

[5] Synthesis and characterization of hydroxyapatite/β-tricalcium phosphate nanocomposites using microwave irradiation [J].

Farzadi, A. ;

Solati-Hashjin, M. ;

Bakhshi, F. ;

Aminian, A. .

CERAMICS INTERNATIONAL, 2011, 37 (01) :65-71

[6] Electrical characterization of hydroxyapatite-based bioceramics [J].

Gittings, J. P. ;

Bowen, C. R. ;

Dent, A. C. E. ;

Turner, I. G. ;

Baxter, F. R. ;

Chaudhuri, J. B. .

ACTA BIOMATERIALIA, 2009, 5 (02) :743-754

[7] Fabrication and Characterization of Carbon Nanotube-Hydroxyapatite Nanocomposite: Application to Anodic Stripping Voltammetric Determination of Cadmium [J].

Pan, Dawei ;

Wang, Yuane ;

Chen, Zhaopeng ;

Yin, Tanji ;

Qin, Wei .

ELECTROANALYSIS, 2009, 21 (08) :944-952

[8] A convenient route for the synthesis of hydroxyapatite through a novel microwave-mediated metathesis reaction [J].

Parhi, P ;

Ramanan, A ;

Ray, AR .

MATERIALS LETTERS, 2004, 58 (27-28) :3610-3612

[9] Layer-by-Layer Polymer Coating of Carbon Nanotubes: Tuning of Electrical Conductivity in Random Networks [J].

Rivadulla, F. ;

Mateo-Mateo, C. ;

Correa-Duarte, M. A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (11) :3751-3755

[10] Ion adsorption behaviour of hydroxyapatite with different crystallinities [J].

Stoetzel, C. ;

Mueller, F. A. ;

Reinert, F. ;

Niederdraenk, F. ;

Barralet, J. E. ;

Gbureck, U. .

COLLOIDS AND SURFACES B-BIOINTERFACES, 2009, 74 (01) :91-95

← 1 2 →