Layer-number determination in graphene by out-of-plane phonons

被引:42
作者
Herziger, Felix [1 ]
May, Patrick [1 ]
Maultzsch, Janina [1 ]
机构
[1] Tech Univ Berlin, Inst Festkorperphys, D-10623 Berlin, Germany
来源
PHYSICAL REVIEW B | 2012年 / 85卷 / 23期
基金
欧洲研究理事会;
关键词
RAMAN-SPECTROSCOPY; BAND-GAP; TRILAYER GRAPHENE; BILAYER GRAPHENE; SCATTERING; THICKNESS; GRAPHITE; RATIO;
D O I
10.1103/PhysRevB.85.235447
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present and discuss a double-resonant Raman mode in few-layer graphene that is able to probe the number of graphene layers. This so-called N mode on the low-frequency side of the G mode results from a double-resonant Stokes-anti-Stokes process combining an longitudinal optical (LO) and an out-of-plane (ZO') phonon. Simulations of the double-resonant Raman spectra in bilayer graphene show very good agreement with the experiments.
引用
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页数:5
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共 34 条
[1]   Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies [J].
Cancado, L. G. ;
Jorio, A. ;
Martins Ferreira, E. H. ;
Stavale, F. ;
Achete, C. A. ;
Capaz, R. B. ;
Moutinho, M. V. O. ;
Lombardo, A. ;
Kulmala, T. S. ;
Ferrari, A. C. .
NANO LETTERS, 2011, 11 (08) :3190-3196
[2]   Raman Spectroscopy of Graphene Edges [J].
Casiraghi, C. ;
Hartschuh, A. ;
Qian, H. ;
Piscanec, S. ;
Georgi, C. ;
Fasoli, A. ;
Novoselov, K. S. ;
Basko, D. M. ;
Ferrari, A. C. .
NANO LETTERS, 2009, 9 (04) :1433-1441
[3]   Electron-phonon coupling and Raman spectroscopy in graphene [J].
Castro Neto, A. H. ;
Guinea, Francisco .
PHYSICAL REVIEW B, 2007, 75 (04)
[4]   Rapid Determination of the Thickness of Graphene Using the Ratio of Color Difference [J].
Chen, Yuan-Fu ;
Liu, Dong ;
Wang, Ze-Gao ;
Li, Ping-Jian ;
Hao, Xin ;
Cheng, Kai ;
Fu, Yao ;
Huang, Le-Xu ;
Liu, Xing-Zhao ;
Zhang, Wan-Li ;
Li, Yan-Rong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (14) :6690-6693
[5]   Raman Characterization of ABA- and ABC-Stacked Trilayer Graphene [J].
Cong, Chunxiao ;
Yu, Ting ;
Sato, Kentaro ;
Shang, Jingzhi ;
Saito, Riichiro ;
Dresselhaus, Gene F. ;
Dresselhaus, Mildred S. .
ACS NANO, 2011, 5 (11) :8760-8768
[6]   Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor [J].
Das, A. ;
Pisana, S. ;
Chakraborty, B. ;
Piscanec, S. ;
Saha, S. K. ;
Waghmare, U. V. ;
Novoselov, K. S. ;
Krishnamurthy, H. R. ;
Geim, A. K. ;
Ferrari, A. C. ;
Sood, A. K. .
NATURE NANOTECHNOLOGY, 2008, 3 (04) :210-215
[7]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[8]   Symmetry properties of vibrational modes in graphene nanoribbons [J].
Gillen, Roland ;
Mohr, Marcel ;
Maultzsch, Janina .
PHYSICAL REVIEW B, 2010, 81 (20)
[9]   Spatially resolved raman spectroscopy of single- and few-layer graphene [J].
Graf, D. ;
Molitor, F. ;
Ensslin, K. ;
Stampfer, C. ;
Jungen, A. ;
Hierold, C. ;
Wirtz, L. .
NANO LETTERS, 2007, 7 (02) :238-242
[10]   Raman scattering from high-frequency phonons in supported n-graphene layer films [J].
Gupta, A. ;
Chen, G. ;
Joshi, P. ;
Tadigadapa, S. ;
Eklund, P. C. .
NANO LETTERS, 2006, 6 (12) :2667-2673