Highly efficient crystalline silicon/Zonyl fluorosurfactant-treated organic heterojunction solar cells

被引：101

作者：

Liu, Qiming ^{[1
]}

Ono, Masahiro ^{[1
]}

Tang, Zeguo ^{[1
]}

Ishikawa, Ryo ^{[1
]}

Ueno, Keiji ^{[1
]}

Shirai, Hajime ^{[1
]}

机构：

[1] Saitama Univ, Grad Sch Sci & Engn, Saitama 3388570, Japan

来源：

APPLIED PHYSICS LETTERS | 2012年 / 100卷 / 18期

关键词：

Organic solar cells - Conducting polymers - Silicon solar cells - Hole mobility - Conductive films - Crystalline materials - Heterojunctions;

D O I：

10.1063/1.4709615

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

We demonstrate a highly efficient hybrid crystalline silicon (c-Si) based photovoltaic devices with hole-transporting transparent conductive poly-(3,4-ethlenedioxythiophene):poly(styrenesufonic acid) (PEDOT:PSS) films, incorporating a Zonyl fluorosurfactant as an additive, compared to non additive devices. The usage of a 0.1% Zonly treated PEDOT: PSS improved the adhesion of precursor solution on hydrophobic c-Si wafer without any oxidation process. The average power conversion efficiency eta value was 10.8%-11.3%, which was superior to those of non-treated devices. Consequently, c-Si/Zonyl-treated PEDOT: PSS heterojunction devices exhibited the highest eta of 11.34%. The Zonyl-treated soluble PEDOT: PSS composite is promising as a hole-transporting transparent conducting layer for c-Si/organic photovoltaic applications. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4709615]

引用

页数：4

共 14 条

[1]

[Anonymous], PHYS SEMICONDUCTOR D

[2]

Avasthi S., 2011, ADV MATER, V23, P5672

[3] High efficiency planar Si/organic heterojunction hybrid solar cells [J].

He, Lining ;

Jiang, Changyun ;

Wang, Hao ;

Lai, Donny ;

Rusli .

APPLIED PHYSICS LETTERS, 2012, 100 (07)

[4]

Ino T., JPN J APPL IN PRESS

[5] Electronic Properties of Transparent Conductive Films of PEDOT:PSS on Stretchable Substrates [J].

Lipomi, Darren J. ;

Lee, Jennifer A. ;

Vosgueritchian, Michael ;

Tee, Benjamin C. -K. ;

Bolander, John A. ;

Bao, Zhenan .

CHEMISTRY OF MATERIALS, 2012, 24 (02) :373-382

[6] Efficient Crystalline Si/Poly(ethylene dioxythiophene): Poly(styrene sulfonate): Graphene Oxide Composite Heterojunction Solar Cells [J].

Ono, Masahiro ;

Tang, Zeguo ;

Ishikawa, Ryo ;

Gotou, Takuya ;

Ueno, Keiji ;

Shirai, Hajime .

APPLIED PHYSICS EXPRESS, 2012, 5 (03)

[7] Spectroscopic ellipsometry studies of the optical properties of doped poly(3,4-ethylenedioxythiophene): An anisotropic metal [J].

Pettersson, LAA ;

Carlsson, F ;

Inganas, O ;

Arwin, H .

THIN SOLID FILMS, 1998, 313 :356-361

[8] Hybrid Heterojunction Solar Cell Based on Organic-Inorganic Silicon Nanowire Array Architecture [J].

Shen, Xiaojuan ;

Sun, Baoquan ;

Liu, Dong ;

Lee, Shuit-Tong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (48) :19408-19415

[9] High-Performance Photoelectrochemical Cells from Ionic Liquid Electrolyte in Methyl-Terminated Silicon Nanowire Arrays [J].

Shen, Xiaojuan ;

Sun, Baoquan ;

Yan, Feng ;

Zhao, Jie ;

Zhang, Fute ;

Wang, Suidong ;

Zhu, Xiulin ;

Lee, Shuittong .

ACS NANO, 2010, 4 (10) :5869-5876

[10] Twenty-two percent efficiency HIT solar cell [J].

Tsunomura, Yasufumi ;

Yoshimine, Yukihiro ;

Taguchi, Mikio ;

Baba, Toshiaki ;

Kinoshita, Toshihiro ;

Kanno, Hiroshi ;

Sakata, Hitoshi ;

Maruyama, Eiji ;

Tanaka, Makoto .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (6-7) :670-673

← 1 2 →