Fabrication of new composite membrane filled with UiO-66 nanoparticles and its application to nanofiltration

被引:56
作者
Dai Xuan Trinh [1 ]
Thuy Phuong Nhat Tran [1 ]
Taniike, Toshiaki [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, 1-1 Asahidai, Nomi, Ishikawa 9231292, Japan
关键词
UiO-66; Metal-organic framework; Composite membrane; Nanofiltration; Rejection mechanism; METAL-ORGANIC FRAMEWORKS; ARTIFICIAL WATER CHANNELS; GRAPHENE OXIDE MEMBRANES; ADSORPTION; STABILITY; CELLULOSE; MOFS; DEGRADATION; PERMEATION; TRANSPORT;
D O I
10.1016/j.seppur.2017.01.004
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new type of MOF-polymer composite membranes was fabricated by depositing UiO-66 nanoparticles into a regenerated cellulose membrane. The UiO-66 nanoparticles filled the pore of the support membrane to offer selective pathways. The filtration performance of the new composite membranes was demonstrated for ultra/nano filtration of methylene blue (MB) and polyethylene glycol of different molecular sizes in aqueous solution. The perfect rejection of MB was attained at extremely high permeation flux compared, with commercially available polymer membranes. The origin of the permeability and rejection was attributed to fluxes passing mainly through the intraparticle porosity of UiO-66 with the size cut-off between 1.22 and 2.28 nm. The unique membrane structure as well as the stability of UiO-66 in water enabled consistent filtration performance against bending and reuse. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:249 / 256
页数:8
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