Synthesis and Crystal Structure of a New Cadmium(II) Complex with 3,4-Pyridinedicarboxylic Acid and 1,4-Bis(imidazol-1-ylmethyl)-butane Ligands

被引：0

作者：

Liu Bo ^{[1
]}

Guo Jia ^{[1
]}

Zhou Shi ^{[1
]}

Wang Qing-Wei ^{[1
]}

Li Xiu-Mei ^{[2
]}

Li Chuan-Bi ^{[1
]}

机构：

[1] Jilin Normal Univ, Minist Educ, Dept Chem, Key Lab Preparat & Applicat Environm Friendly Mat, Siping 136000, Peoples R China

[2] Tonghua Teachers Coll, Dept Chem, Tonghua 134002, Jilin, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 12期

关键词：

hydrothermal synthesis; crystal structure; coordination polymer; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; LUMINESCENT PROPERTIES; SEPARATION; ZINC(II);

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metal-organic coordination polymer [Cd(PDB)(bimb)](n) (H2PDB = 3,4-pyridinedicarboxylic acid, bimb = 1,4-bis(imidazol-1-ylmethyl)-butane) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Yellow crystals crystallize in the monoclinic system, space group Cc with a = 19.001(5), b = 7.948(2), c = 13.392(4) angstrom, beta = 120.803(3)degrees, V = 1737.0(8) angstrom(3), C17H17CdN5O4, M-r = 467.76, D-c = 1.789 g/cm(3), F(000) = 936, Z = 4, mu(MoK alpha) = 1.293 mm(-1), the final R = 0.0266 and wR = 0.0534 for 2707 observed reflections (I > 2 sigma(I). The structure of 1 exhibits a three-dimensional network structure.

引用

页码：1752 / 1756

页数：5

共 50 条

[31] Synthesis and Crystal Structure of a New Zn(II) Interpenetrating Complex Based on 1,4-bis(2-methyl-imidazol-1-yl) butane and 5-bromoisophthalic Acid
Wang, Hua-Rui
Guo, Hui
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (10) : 1457 - 1460
[32] Synthesis, Crystal Structure and Theoretical Calculations of a Cadmium(II) Coordination Polymer Assembled by 4,4′-Oxydibenzoic Acid and 1,3-Bis(imidazol-1-ylmethyl)-Benzene Ligands
Xiu-Mei Li
Qing-Wei Wang
Pei-Ying Zhan
Ya-Ru Pan
Journal of Chemical Crystallography, 2016, 46 : 163 - 169
[33] Synthesis, Crystal Structure and Theoretical Calculations of a Cadmium(II) Coordination Polymer Assembled by 4,4′-Oxydibenzoic Acid and 1,3-Bis(imidazol-1-ylmethyl)Benzene Ligands
Li, Xiu-Mei
Wang, Qing-Wei
Zhan, Pei-Ying
Pan, Ya-Ru
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2016, 46 (04) : 163 - 169
[34] Poly[[sesqui[μ2-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N:N′](carbonato-κ2O,O′)copper(II)] 1,4-bis(imidazol-1-ylmethyl)benzene hemisolvate pentahydrate]
Dai, Yu-Mei
Tang, En
Huang, Jin-Feng
Yang, Qiu-Yan
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2008, 64 (10): : M349 - M352
[35] Syntheses and structural characterization of iron(II) coordination polymers with flexible 1,4-bis(imidazol-1-ylmethyl) benzene ligand
Beheshti, Azizolla
Lalegani, Arash
Bruno, Giuseppe
Rudbari, Hadi Amiri
Nobakht, Valiollah
INORGANICA CHIMICA ACTA, 2013, 408 : 214 - 221
[36] CRYSTAL STRUCTURE OF 1,4-BIS(IODODIPHENYLTIN)BUTANE
CODY, V
COREY, ER
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1969, 19 (02) : 359 - &
[37] Poly[[μ2-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ4-cyclohexane-1,4-dicarboxylato)dicobalt(II)]
Yu, Qun-Di
Sun, Da-Jun
Tiekink, Edward R. T.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1165 - +
[38] Poly[bis[μ-1,4-bis(imidazol-1-yl)butane]dicyanatonickel(II)]
Zhu, Xia
Zhang, Yu-Mei
Li, Bao-Long
Zhang, Yong
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : m921 - m923
[39] Poly[bis[μ-1,4-bis(imidazol-1-yl)butane]dicyanatocadmium(II)]
Zhu, Xia
Guo, Ying
Zou, Yun-Ling
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1506 - U140
[40] Coordination polymers built from 1,4-bis(imidazol-1-ylmethyl)benzene: from crystalline to amorphous
Adarsh, N. N.
Novio, Fernando
Ruiz-Molina, Daniel
DALTON TRANSACTIONS, 2016, 45 (28) : 11233 - 11255

← 1 2 3 4 5 →