Synthesis and Crystal Structure of a New Cadmium(II) Complex with 3,4-Pyridinedicarboxylic Acid and 1,4-Bis(imidazol-1-ylmethyl)-butane Ligands

被引：0

作者：

Liu Bo ^{[1
]}

Guo Jia ^{[1
]}

Zhou Shi ^{[1
]}

Wang Qing-Wei ^{[1
]}

Li Xiu-Mei ^{[2
]}

Li Chuan-Bi ^{[1
]}

机构：

[1] Jilin Normal Univ, Minist Educ, Dept Chem, Key Lab Preparat & Applicat Environm Friendly Mat, Siping 136000, Peoples R China

[2] Tonghua Teachers Coll, Dept Chem, Tonghua 134002, Jilin, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 12期

关键词：

hydrothermal synthesis; crystal structure; coordination polymer; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; LUMINESCENT PROPERTIES; SEPARATION; ZINC(II);

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metal-organic coordination polymer [Cd(PDB)(bimb)](n) (H2PDB = 3,4-pyridinedicarboxylic acid, bimb = 1,4-bis(imidazol-1-ylmethyl)-butane) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Yellow crystals crystallize in the monoclinic system, space group Cc with a = 19.001(5), b = 7.948(2), c = 13.392(4) angstrom, beta = 120.803(3)degrees, V = 1737.0(8) angstrom(3), C17H17CdN5O4, M-r = 467.76, D-c = 1.789 g/cm(3), F(000) = 936, Z = 4, mu(MoK alpha) = 1.293 mm(-1), the final R = 0.0266 and wR = 0.0534 for 2707 observed reflections (I > 2 sigma(I). The structure of 1 exhibits a three-dimensional network structure.

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页码：1752 / 1756

页数：5

相关论文

共 21 条

[1] In(OH)BDC•0.75BDCH2 (BDC = benzenedicarboxylate), a hybrid inorganic-organic vernier structure [J].

Anokhina, EV ;

Vougo-Zanda, M ;

Wang, XQ ;

Jacobson, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) :15000-15001

[2]

[Anonymous], 1988, WINDOWS PROGRAM CRYS

[3] Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates [J].

Chen, W ;

Wang, JY ;

Chen, C ;

Yue, Q ;

Yuan, HM ;

Chen, JS ;

Wang, SN .

INORGANIC CHEMISTRY, 2003, 42 (04) :944-946

[4] Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4'-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands [J].

Devereux, Michael ;

Shea, Denis O. ;

Kellett, Andrew ;

McCann, Malachy ;

Walsh, Maureen ;

Egan, Denise ;

Deegan, Carol ;

Kgdziora, Kinga ;

Rosair, Georgina ;

Muelller-Bunz, Helge .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2007, 101 (06) :881-892

[5] Utility and synthetic uses of Mannich reaction: An efficient route for synthesis of thiadiazino-[1,3,5][3,2-a]benzimidazoles [J].

El-Wareth, A ;

Sarhan, AO ;

Abdel-Hafez, SH ;

El-Sherief, H ;

Aboel-Fadl, T .

SYNTHETIC COMMUNICATIONS, 2006, 36 (08) :987-996

[6] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[7] Three-periodic nets and tilings: regular and quasiregular nets [J].

Friedrichs, OD ;

O'Keeffe, M ;

Yaghi, OM .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2003, 59 :22-27

[8]

Fu ZY, 2002, EUR J INORG CHEM, P2730

[9] Influence of the reaction temperature and pH on the coordination modes of the 1,4-benzenedicarboxylate (BDC) ligand:: A case study of the NiII(BDC)/2,2′-bipyridine system [J].

Go, YB ;

Wang, XQ ;

Anokhina, EV ;

Jacobson, AJ .

INORGANIC CHEMISTRY, 2005, 44 (23) :8265-8271

[10] Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks [J].

He, JH ;

Yu, JH ;

Zhang, YT ;

Pan, QH ;

Xu, RR .

INORGANIC CHEMISTRY, 2005, 44 (25) :9279-9282