Synthesis and Crystal Structure of a New Cadmium(II) Complex with 3,4-Pyridinedicarboxylic Acid and 1,4-Bis(imidazol-1-ylmethyl)-butane Ligands

被引：0
|
作者：
Liu Bo [1 ]
Guo Jia [1 ]
Zhou Shi [1 ]
Wang Qing-Wei [1 ]
Li Xiu-Mei [2 ]
Li Chuan-Bi [1 ]
机构：
[1] Jilin Normal Univ, Minist Educ, Dept Chem, Key Lab Preparat & Applicat Environm Friendly Mat, Siping 136000, Peoples R China
[2] Tonghua Teachers Coll, Dept Chem, Tonghua 134002, Jilin, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 12期
关键词：
hydrothermal synthesis; crystal structure; coordination polymer; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; LUMINESCENT PROPERTIES; SEPARATION; ZINC(II);
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A metal-organic coordination polymer [Cd(PDB)(bimb)](n) (H2PDB = 3,4-pyridinedicarboxylic acid, bimb = 1,4-bis(imidazol-1-ylmethyl)-butane) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Yellow crystals crystallize in the monoclinic system, space group Cc with a = 19.001(5), b = 7.948(2), c = 13.392(4) angstrom, beta = 120.803(3)degrees, V = 1737.0(8) angstrom(3), C17H17CdN5O4, M-r = 467.76, D-c = 1.789 g/cm(3), F(000) = 936, Z = 4, mu(MoK alpha) = 1.293 mm(-1), the final R = 0.0266 and wR = 0.0534 for 2707 observed reflections (I > 2 sigma(I). The structure of 1 exhibits a three-dimensional network structure.
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页码：1752 / 1756
页数：5
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