Dependence of circularly polarized luminescence due to the neighboring effects of binaphthyl units with the same axial chirality

被引:38
作者
Amako, Tomoyuki [1 ]
Kimoto, Takaya [1 ]
Tajima, Nobuo [2 ]
Fujiki, Michiya [3 ]
Imai, Yoshitane [1 ]
机构
[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Osaka 5778502, Japan
[2] Natl Inst Mat Sci, Computat Mat Sci Ctr, Tsukuba, Ibaraki 3050047, Japan
[3] Nara Inst Sch & Technol Takayama, Grad Sch Mat Sci, Nara 6300192, Japan
关键词
CORRELATED MOLECULAR CALCULATIONS; GAUSSIAN-BASIS SETS; CPL PROPERTIES; COMPLEXES; STATES;
D O I
10.1039/c3ra23198d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The solution-dissolved-state circular dichroism (CD) and the circularly polarized luminescence (CPL) of chiral binaphthyl fluorophores was controlled by both the axial chirality of the binaphthyl units as well as by the effect of neighboring binaphthyl units.
引用
收藏
页码:6939 / 6944
页数:6
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