Phenylene Vinylene Platinum(II) Acetylides with Prodigious Two-Photon Absorption

被引：90

作者：

Dubinina, Galyna G. ^{[1
]}

Price, Randi S. ^{[1
]}

Abboud, Khalil A. ^{[1
]}

Wicks, Geoffrey ^{[2
]}

Wnuk, Pawel ^{[3
]}

Stepanenko, Yuriy ^{[3
]}

Drobizhev, Mikhail ^{[2
]}

Rebane, Aleksander ^{[2
,4
]}

Schanze, Kirk S. ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Montana State Univ, Dept Phys, Bozeman, MT 59717 USA

[3] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

[4] NICPB, EE-12618 Tallinn, Estonia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 47期

基金：

美国国家科学基金会;

关键词：

NONLINEAR ABSORPTION; SINGLET OXYGEN; CHROMOPHORES; SPECTROSCOPY; LUMINESCENCE; COMPLEXES;

D O I：

10.1021/ja309393c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The linear and nonlinear optical properties.. of a series of linear and cross-conjugated platinum(II) acetylide complexes that contain extended p-(phenylene vinylene) chromophores are reported. The complexes exhibit very high femtosecond two photon absorption (2PA) cross Section values (sigma(2) up to 10 000 GM), as measured by nonlinear transmission (NLT) and two-photon excited fluorescence (2PEF) methods. The large 2PA cross sections span a broad range of wavelengths, 570-810 nm, and they overlap with the triplet excited. state absorption. Spectral coincidence of high cross section 2PA and triplet absorption is a key feature giving rise to efficient dual-mode optical power limiting (OPL).

引用

页码：19346 / 19349

页数：4

共 50 条

[21] Three new five-coordinated mercury (II) dyes: Structure and enhanced two-photon absorption
Zhou, Hongping
Zhou, Feixia
Wu, Peng
Zheng, Zheng
Yu, Zhipeng
Chen, Yixin
Tu, Yulong
Kong, Lin
Wu, Jieying
Tian, Yupeng
DYES AND PIGMENTS, 2011, 91 (02) : 237 - 247
[22] Two-photon interband absorption coefficients in tungstate and molybdate crystals
Lukanin, V. I.
Karasik, A. Ya.
OPTICS COMMUNICATIONS, 2015, 336 : 207 - 212
[23] Conjugated Polymers with Two-Photon Absorption for Bioimaging
Ren Xiaojie
Lu Xiaomei
Fan Quli
Huang Wei
PROGRESS IN CHEMISTRY, 2013, 25 (10) : 1739 - 1750
[24] Two-photon Absorption and Photoionization of a Bacterial Phytochrome
Do, Thanh Nhut
Menendez, David
Bizhga, Dorina
Stojkovic, Emina A.
Kennis, John T. M.
JOURNAL OF MOLECULAR BIOLOGY, 2024, 436 (05)
[25] TWO-PHOTON ABSORPTION AND APPLICATIONS TO BIOLOGICAL SYSTEMS
Collins, J.
BIOPHOTONICS: SPECTROSCOPY, IMAGING, SENSING, AND MANIPULATION, 2011, : 261 - 285
[26] Two-Photon Absorption in Conjugated Energetic Molecules
Bjorgaard, Josiah A.
Sifain, Andrew E.
Nelson, Tammie
Myers, Thomas W.
Veauthier, Jacqueline M.
Chavez, David E.
Scharff, R. Jason
Tretiak, Sergei
JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 120 (26) : 4455 - 4464
[27] Two-photon absorption in arsenic sulfide glasses
Chunaev, D. S.
Snopatin, G. E.
Plotnichenko, V. G.
Karasik, A. Ya
QUANTUM ELECTRONICS, 2016, 46 (10) : 895 - 898
[28] Two-photon absorption spectra of carotenoids compounds
Vivas, Marcelo Goncalves
Silva, Daniel Luiz
de Boni, Leonardo
Zalesny, Robert
Bartkowiak, Wojciech
Mendonca, Cleber Renato
JOURNAL OF APPLIED PHYSICS, 2011, 109 (10)
[29] Stereochemical Effects on Platinum Acetylide Two-Photon Chromophores
Shelton, Abigail H.
Valandro, Silvano R.
Price, Randi S.
Dubinina, Galyna G.
Abboud, Khalil A.
Wicks, Geoffrey
Rebane, Aleksander
Younus, Muhammad
Schanze, Kirk S.
JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 123 (43) : 9382 - 9393
[30] One- and Two-Photon Spectra of Platinum Acetylide Chromophores: A TDDFT Study
Nguyen, Kiet A.
Day, Paul N.
Pachter, Ruth
JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (50) : 13943 - 13952

← 1 2 3 4 5 →