Synthesis of a graphene/polyaniline/MCM-41 nanocomposite and its application as a supercapacitor

被引:64
作者
Feng, Xiaomiao [1 ]
Yan, Zhenzhen [1 ]
Chen, Ningna [1 ]
Zhang, Yu [1 ]
Liu, Xingfen [1 ]
Ma, Yanwen [1 ]
Yang, Xiaoyan [2 ]
Hou, Wenhua [2 ]
机构
[1] Nanjing Univ Posts & Telecommun, Sch Mat Sci & Engn, Inst Adv Mat, Key Lab Organ Elect & Informat Displays, Nanjing 210046, Jiangsu, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, MOE, Key Lab Mesoscop Chem, Nanjing 210093, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
WALLED CARBON NANOTUBES; REDUCED GRAPHENE OXIDE; HIGH-PERFORMANCE; ELECTROCHEMICAL SUPERCAPACITORS; ELECTRODE MATERIAL; POLYANILINE; COMPOSITE; FILMS; POLYMERIZATION; CONDUCTIVITY;
D O I
10.1039/c3nj00108c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A ternary nanocomposite of graphene/polyaniline (PANI)/porous silica MCM-41 (MCM-41) was prepared by a hydrothermal method. The amount of graphene oxide (GO) in the graphene/PANI/MCM-41 nanocomposite had a strong effect on the supercapacitor performance. The experimental results showed that the specific capacitance of the graphene/PANI/MCM-41 nanocomposite could reach the highest value when the GO content was 50%. The specific capacitance of the nanocomposite was 405 F g(-1) at a current density of 0.8 A g(-1). Furthermore, over 91.4% of the original capacitance was retained after repeating the galvanostatic charge-discharge for 1000 cycles. The performance of the prepared supercapacitor containing different amounts of GO were studied in detail.
引用
收藏
页码:2203 / 2209
页数:7
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