The interaction of α-hydroxycarboxylic acids with metal ions:: Lactic acid (H2L1) and 2-methyllactic acid (H2L2) with cobalt(II) crystal and molecular structures of [Co(HL1)2(H2O)2]•H2O and [Co(HL2)2(H2O)2]

被引：0
作者：
Carballo, R [1 ]
Covelo, B [1 ]
Vázquez-López, EM [1 ]
机构：
[1] Univ Vigo, Dept Quim Inorgan, Fac Ciencias Quim, E-36200 Vigo, Spain
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 02期
关键词：
cobalt; alpha-hydroxycarboxylato ligands; crystal structure; thermochemistry;
D O I：
10.1002/1521-3749(200202)628:2<468::AID-ZAAC468>3.0.CO;2-J
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cobalt(II) complexes [Co(HL1)(2)(H2O)(2)].H2O) (1) and [Co(HL2)(2)(H2O)(2)] (2) [(HL1)(-) = (+/-)-lactate, (HL2)(-) = 2-Methyl- lactate] were prepared. and characterized structurally. The cobalt atom is in a distorted octahedral environment in both compounds. Both alpha-hydroxycarboxylato ligands are O,O'-bidentate chelating monoanions. The presence of a lattice water molecule in 1 makes its supramolecular organization different from that of 2. The thermal behaviour of both compounds was also investigated.
引用
收藏
页码：468 / 472
页数：5
相关论文
共 50 条
  • [31] Synthesis and crystal structure of [SmN(CH2COO)3(H2O)2]•H2O
    Chen, Y
    Liu, QD
    Li, JR
    Gao, S
    Liu, H
    Zhang, YJ
    Yu, KB
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (06) : 400 - 404
  • [32] Synthesis, crystal structure and electrochemical properties of [Cu(NPA)2(Im)2(H2O)]•H2O
    Li Dong-Ping
    Chen Zhi-Min
    Kung Yun-Fei
    Kuang Dai-Zhi
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (05) : 892 - 896
  • [33] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
    Zheng, YQ
    Kong, ZP
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
  • [34] Synthesis and Crystal Structure of the Mixed Metal Coordination Framework [Co2(H2O)2(pyrazine)V4O12](H2O)2
    Severance, Rachel C.
    Rountree, Eric S.
    Smith, Mark D.
    zur Loye, Hans-Conrad
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2012, 42 (10) : 997 - 1000
  • [35] Synthesis, Crystal Structure and Luminescence Property of [Co（hmz）2（H2O）4]·2H2O
    张曙光
    冯云龙
    温一航
    苏虹
    Chinese Journal of Structural Chemistry, 2007, (06) : 664 - 668
  • [36] Crystal structure and properties of a new sandwich heteropolytungstate Na6(C5N2H7){[Na(H2O)2]3Co(H2O)5[CO(H2O)]3(AsW9O33)2}•27H2O
    Shang Jun-Fei
    Ren Shu-Hua
    Zhen Yan-Zhong
    Fu Feng
    Wang Ji-Wua
    Xue Gang-Lin
    ACTA CHIMICA SINICA, 2008, 66 (02) : 205 - 210
  • [37] Synthesis, crystal structure and luminescence property of [Co(hmz)2(H2O)4]•2H2O
    Zhang Shu-Guang
    Feng Yun-Long
    Wen Yi-Hang
    Hong, Su
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (06) : 664 - 668
  • [38] Synthesis and crystal structure of [Co(pyr)2(sal)2]•H2O
    Zhong, F
    Zhang, SH
    Jiang, YM
    Zhong, XX
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (03) : 318 - 320
  • [39] Structures of [GPGG + H - H2O]+ and [GPGG + H - H2O - NH=CH2]+ ions; evidence of rearrangement prior to dissociation
    Lau, Justin Kai-Chi
    Lai, Cheuk-Kuen
    Lam, K. H. Brian
    Chu, Ivan K.
    Martens, Jonathan
    Berden, Giel
    Oomens, Jos
    Hopkinson, Alan C.
    Siu, K. W. Michael
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2019, 442 : 51 - 57
  • [40] Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V15O42(H2O)]•2H2O
    Cui, XB
    Xu, JQ
    Ding, L
    Ding, H
    Ye, L
    Yang, GY
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 660 (1-3) : 131 - 137
12345