Photoelectrochemically-assisted biofuel cell constructed by redox complex and g-C3N4 coated MWCNT bioanode
被引:26
作者:
Cakiroglu, Bekir
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Univ Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, France
Sakarya Univ, Biomed Magnet & Semicond Mat Res Ctr BIMAS RC, TR-54187 Sakarya, TurkeyUniv Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, France
Cakiroglu, Bekir
[1
,2
]
Chauvin, Jerome
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机构:
Univ Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, FranceUniv Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, France
Chauvin, Jerome
[1
]
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Le Goff, Alan
[1
,4
]
Gorgy, Karine
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机构:
Univ Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, FranceUniv Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, France
Gorgy, Karine
[1
]
Ozacar, Mahmut
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Sakarya Univ, Biomed Magnet & Semicond Mat Res Ctr BIMAS RC, TR-54187 Sakarya, Turkey
Sakarya Univ, Sci & Arts Fac, Dept Chem, TR-54187 Sakarya, TurkeyUniv Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, France
Ozacar, Mahmut
[2
,3
]
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Holzinger, Michael
[1
,4
]
机构:
[1] Univ Grenoble Alpes, DCM UMR 5250, F-38000 Grenoble, France
[2] Sakarya Univ, Biomed Magnet & Semicond Mat Res Ctr BIMAS RC, TR-54187 Sakarya, Turkey
[3] Sakarya Univ, Sci & Arts Fac, Dept Chem, TR-54187 Sakarya, Turkey
Herein, we report a membraneless glucose and air photoelectrochemical biofuel cell (PBFC) with a visible light assisted photobioanode. Flavin adenine dinucleotide dependent glucose dehydrogenase (FADGDH) was immobilized on the combined photobioanode for the visible light assisted glucose oxidation (GCE vertical bar MWCNT vertical bar g-C3N4 vertical bar Ru-complex vertical bar FADGDH) with a quinone mediated electron transfer. Bilirubine oxidase (BOx) immobilized on MWCNT coated GCE (GCE vertical bar BOx) was used as the cathode with direct electron transfer (DET). An improvement of biocatalytic oxidation current was observed by 6.2% due in part to the light-driven electron-transfer. The large oxidation currents are probably owing to the good contacting of the immobilized enzymes with the electrode material and the utilization of light assisted process. Under the visible light, the photobioanode shows an anodic photocurrent of 1.95 mu A cm(2) at attractively low potentials viz. -0.4 vs Ag/AgCl. The lower-lying conduction band of g-C3N4 as compared to Ru-complexes decreases the rate of hole and electron recombination and enhances the charge transportation. The bioanode shows maximum current density for glucose oxidation up to 6.78 mu A cm(-2) at 0.2 V vs Ag/AgCl at pH:7. The performance of three promising Ru-complexes differing in chemical and redox properties were compared as electron mediators for FADGDH. Upon illumination, the PBFC delivered a maximum power density of 28.5 +/- 0.10 mu W cm(-2) at a cell voltage of +0.4 V with an open circuit voltage of 0.64 V.
机构:
Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USAUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
Milton, Ross D.
Hickey, David P.
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机构:
Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USAUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
Hickey, David P.
De Andrade, Adalgisa R.
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Univ Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, BrazilUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
De Andrade, Adalgisa R.
Minteer, Shelley D.
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h-index: 0
机构:
Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USAUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Fac Sci Monastir, Lab Phys & Chim Interfaces, Monastir, TunisiaCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Bourourou, Mariem
Elouarzaki, Kamal
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Elouarzaki, Kamal
Holzinger, Michael
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h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Holzinger, Michael
Agnes, Charles
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Agnes, Charles
Le Goff, Alan
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h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Le Goff, Alan
Reverdy-Bruas, Nadege
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机构:
CNRS UMR 5518, Grenoble INP Pagora, Lab Pulp & Paper Sci & Graph Arts LGP2, F-38402 St Martin Dheres, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Reverdy-Bruas, Nadege
Chaussy, Didier
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h-index: 0
机构:
CNRS UMR 5518, Grenoble INP Pagora, Lab Pulp & Paper Sci & Graph Arts LGP2, F-38402 St Martin Dheres, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Chaussy, Didier
Party, Mikael
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h-index: 0
机构:
CNRS UMR 5518, Grenoble INP Pagora, Lab Pulp & Paper Sci & Graph Arts LGP2, F-38402 St Martin Dheres, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Party, Mikael
Maaref, Abderrazak
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h-index: 0
机构:
Fac Sci Monastir, Lab Phys & Chim Interfaces, Monastir, TunisiaCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Maaref, Abderrazak
Cosnier, Serge
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
机构:
Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USAUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
Milton, Ross D.
Hickey, David P.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USAUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
Hickey, David P.
De Andrade, Adalgisa R.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, BrazilUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
De Andrade, Adalgisa R.
Minteer, Shelley D.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USAUniv Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Fac Sci Monastir, Lab Phys & Chim Interfaces, Monastir, TunisiaCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Bourourou, Mariem
Elouarzaki, Kamal
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Elouarzaki, Kamal
Holzinger, Michael
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Holzinger, Michael
Agnes, Charles
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Agnes, Charles
Le Goff, Alan
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Le Goff, Alan
Reverdy-Bruas, Nadege
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UMR 5518, Grenoble INP Pagora, Lab Pulp & Paper Sci & Graph Arts LGP2, F-38402 St Martin Dheres, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Reverdy-Bruas, Nadege
Chaussy, Didier
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UMR 5518, Grenoble INP Pagora, Lab Pulp & Paper Sci & Graph Arts LGP2, F-38402 St Martin Dheres, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Chaussy, Didier
Party, Mikael
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UMR 5518, Grenoble INP Pagora, Lab Pulp & Paper Sci & Graph Arts LGP2, F-38402 St Martin Dheres, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Party, Mikael
Maaref, Abderrazak
论文数: 0引用数: 0
h-index: 0
机构:
Fac Sci Monastir, Lab Phys & Chim Interfaces, Monastir, TunisiaCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France
Maaref, Abderrazak
Cosnier, Serge
论文数: 0引用数: 0
h-index: 0
机构:
CNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, FranceCNRS UJF, UMR 5250, Dept Chim Mol, F-38041 Grenoble, France